In this work, a new mixed-ligand binuclear Co(II) complex of Schiff base was prepared. Moreover, the characterization of this prepared complex was performed by measurement of melting points, UV-Vis spectra, FT-IR spectra, and magnetic susceptibility measurements, and later compared with metal and ligand solutions. It has been discovered that the Schiff bases with Co(II) ion forms a binuclear complex with a stoichiometry of molar ratio 1:2 from ?metal:ligand?. The photodecolorization of this complex was done under UV light for ZnO's suspension solution. The results of this photodecolorization showed that the greatest efficiency was obtained with the use of ZnO dose of 300 mg/100 mL and at an initial pH of 7. The decolorization activation energy for this complex is a small value of 11.289 kJ mol?1. Additionally, the thermodynamic study for this reaction is non-spontaneous, endothermic and less random.
Published by | Universitas Gadjah Mada |
Journal Name | Indonesian Journal of Chemistry |
Contact Phone | - |
Contact Name | - |
Contact Email | - |
Location | Kab. sleman, Daerah istimewa yogyakarta INDONESIA |
Website | ijc| https://journal.ugm.ac.id/index.php/ijc| |
ISSN | ISSN : 14119420, EISSN : 24601578, DOI : -, |
Core Subject | Science, Engineering, |
Meta Subject | Chemical Engineering, Chemistry & Bioengineering, Chemistry, |
Meta Desc | Indonesian Journal of Chemistry is an International, peer-reviewed, open access journal that publishes original research articles, review articles, as well as short communication in all areas of chemistry including applied chemistry. The journal is accredited by The Ministry of Research, Technology and Higher Education (RISTEKDIKTI) No : 21/E/KPT/2018 (in First Rank) and indexed in Scopus since 2012. Since 2018 (Volume 18), Indonesian Journal of Chemistry publish four issues (numbers) annually (February, May, August and November). |
Penulis | Abass, Suhad Kareem , Al-Hilfi, Jassim Abbas , Abbas, Sawsan Khudhair , Ahmed, Luma Majeed |
Publisher Article | Universitas Gadjah Mada |
Subtitle Article | Indonesian Journal of Chemistry Vol 20, No 2 (2020) |
Scholar Google | http://scholar.google.com/scholar?q=%2Bintitle%3A&… |
View Article | https://journal.ugm.ac.id/ijc/… |
DOI | https://doi.org/10.22146/ijc.44192 |
DOI Number | DOI: 10.22146/ijc.44192 |
Download Article [1] | https://journal.ugm.ac.id/ijc/article/do… |
Download Article [2] | http://download.garuda.ristekdikti.go.id… |
Informasi yang terkait dengan PREPARATION, CHARACTERIZATION AND STUDY OF THE PHOTODECOLORIZATION OF MIXED LIGAND BINUCLEAR CO(II) COMPLEX OF SCHIFF BASE BY ZNO
The Preparation