磷酸钚(III)是一种无机化合物,为钚的磷酸盐之一,化学式PuPO4。
制备
磷酸钚(III)可由二氧化钚和磷酸氢二铵在1000 °C反应得到,产物可能由于原料241Pu的衰变而带有很少的镅。[1]磷酸硼和二氧化钚反应则会得到磷酸钚(III)和焦磷酸钚(IV)的混合物;[2]若和三氟化钚高温反应,可以得到纯净的磷酸钚(III):[3]
- PuF3 + BPO4 → PuPO4 + BF3
在盐酸介质中,Pu3+和磷酸二氢钠反应,可以沉淀出PuPO4的水合物。[4]
参考文献
- ^ 1.0 1.1 1.2 K E Wright, K Popa, P Pöml. Synthesis and characterisation of PuPO 4 - a potential analytical standard for EPMA actinide quantification. IOP Conference Series: Materials Science and Engineering. 2018-01, 304: 012020 [2019-06-21]. ISSN 1757-8981. doi:10.1088/1757-899X/304/1/012020.
- ^ C. E. Bamberger. Preparation of Metal Phosphates by Metathesis Reaction with BPO4. Journal of the American Ceramic Society. 1982-07, 65 (7): c107–c108 [2019-06-21]. ISSN 0002-7820. doi:10.1111/j.1151-2916.1982.tb10477.x (英语).
- ^ C.E. Bamberger, R.G. Haire, H.E. Hellwege, G.M. Begun. Synthesis and characterization of crystalline phosphates of plutonium(III) and plutonium(IV). Journal of the Less Common Metals. 1984-02, 97: 349–356 [2019-06-21]. doi:10.1016/0022-5088(84)90040-7. (原始内容存档于2018-06-30) (英语).
- ^ Dhanpat Rai, Dean A. Moore, Andrew R. Felmy, Kevin M. Rosso, Harvey Bolton. PuPO4(cr, hyd.) Solubility Product and Pu3+ Complexes with Phosphate and Ethylenediaminetetraacetic Acid. Journal of Solution Chemistry. 2010-06, 39 (6): 778–807 [2019-06-21]. ISSN 0095-9782. doi:10.1007/s10953-010-9541-x (英语).