Fumarole mineral

Fumarole formation of tazieffite [de] acicular crystals (black) at Mutnovsky, Kamchatka. An electron micrograph, colour enhanced by optical microscopy, depicted width: 700 microns.

Fumarole minerals (or fumarolic minerals) are minerals which are deposited by fumarole exhalations. They form when gases and compounds desublimate or precipitate out of condensates, forming mineral deposits. They are mostly associated with volcanoes (as volcanic sublimate or fumarolic sublimate) following deposition from volcanic gas during an eruption or discharge from a volcanic vent or fumarole,[1] but have been encountered on burning coal deposits as well. They can be black or multicoloured and are often unstable upon exposure to the atmosphere.

Native sulfur, in this context called brimstone, is a common sublimate mineral and various halides, sulfides and sulfates occur in this environment associated with fumaroles and eruptions. A number of rare minerals are fumarole minerals, and at least 240 such minerals are known from Tolbachik volcano in Kamchatka, Russia. Other volcanoes where particular fumarole minerals have been discovered are Vulcano in Italy and Bezymyanny also in Russia.

Origin and appearance

Fumarole minerals in SEM images, from Mutnovsky volcano in Kamchatka. An electron micrograph, colour enhanced by optical microscopy, depicted width: 700 microns.

In fumaroles, minerals either form through desublimation from fumarole gases or through interactions of fumarole gases with country rock.[2] The former are known as sublimates and the latter as incrustations.[3] Some such deposits may also form through the interaction between liquid fumarole condensates and country rock[4] and are not always formed by desublimation.[5] Repeated cycles of primary deposition and secondary alteration may occur.[6] Volcanic gases such as hydrogen chloride, hydrogen fluoride, sulfur dioxide and water[7] can transport large amounts of elements, thus contributing to geochemical cycles on the surface and the formation of ore deposits at depth.[8] When these exhalations reach the atmosphere and cool, the minerals contained in them tend to precipitate out.[9]

Volcanic fumarole minerals (as volcanic sublimate or fumarolic sublimate) form following deposition from volcanic gas during an eruption or discharge from a volcanic vent or fumarole.[1] Burning coal produces enough heat to partially melt rocks and to generate exhalations of the mineral components embedded in coal.[10] Coal seam fires often deposit fumarolic minerals over areas of a few square metres which can be detected by airborne hyperspectral imagery.[11] Coal fires can mobilize toxic trace elements.[12] Fumarole minerals have also been found in Gusev crater on Mars[13] and possibly in a sample returned from the Moon by the probe Chang'e-5.[14]

Fumarole deposits have been used to identify heat flow anomalies and to reconstruct ore genesis processes.[6]

Fumarole exhalations are often black or multicoloured, and tend to develop typical zonations. Common components are sulfur compounds and elemental sulfur.[9] In the Valley of Ten Thousand Smokes in Alaska the fumarole minerals form both thin crusts in the vents, mixtures with tephra deposits[15] and coloured outcrops and mounds at the sites of former fumaroles.[16] Deposits at Tolbachik volcano have shapes likef crusts, small plates[17] and globules.[18]

Typical components of fumarole minerals are halides, oxides, sulfates and sulfides,[19] with the exact composition different between volcanoes, individual vents at volcanoes and different temperatures of the same vent.[20][21] Fumarolic minerals are often unstable and are eroded or decompose,[22] in the Valley of Ten Thousand Smokes in Alaska it took less than a century for almost all fumarole mineral deposits to disappear[23] although others remained and were later used to identify former fumarole vents.[24] Thus, many fumarole minerals are rare and many rare minerals are fumarole minerals.[25] Some fumarolic minerals have been found in extinct Cenozoic volcanoes[26] and could exist in Archean rocks as well, however.[27] Unique textures occur such as bubble-like structures, which may form when the liquid that deposits the minerals evaporates.[4]

Volcanoes

Electron micrograph images of fumarolic minerals at Mutnovsky volcano, Kamchatka

Research on the mineralogy of fumarole minerals has been conducted in Central America, Russia and Europe,[19] with detailed publications on Izalco in El Salvador,[28] Eldfell in Iceland,[29] Vesuvius[20] where research goes back to the early 19th century[30] and Vulcano in Italy, Mount Usu in Japan, Kudryavy and Tolbachik in Russia, Kilauea and Mount St. Helens in the United States.[19] Sulfur deposits containing fumarolic desublimates are found at Guallatiri and Lastarria volcanoes in the Central Volcanic Zone of the Andes.[31] Kudryavy volcano in the Kurils is particularly known for the numerous mineralizations its fumaroles have produced[32] and for the presence of rhenium-rich precipitates.[3] Among the elements found there are copper-gold-silver alloys.[33] Various sulfate-based minerals have been identified at the Salton Buttes in California.[34] Fumarolic minerals have also been reported from the Western Andes in Bolivia.[35]

The most fumarolic minerals have been found at Tolbachik volcano in Kamchatka, Russia; Tolbachik also has one of the most diverse mineral assemblages in the world,[26] with a number of "endemic" minerals.[36] The high temperature and oxidizing regime of exhalations which transport the elements at Tolbachik facilitates mineral deposition.[37] A large assemblage of silicates[38] and a number of copper-zinc selenite chlorides[39] and copper-based fumarolic minerals were discovered at Tolbachik volcano, Kamchatka, Russia. Many of these include polymeric CuO
₄ units.[2] About 240 minerals have been identified at Tolbachik,[26] close to a record,[40] 40 of them only incompletely studied.[41] Elemental gold linked to chlorides at Tolbachik has been interpreted as gold transported by chlorine-rich oxidizing environments.[42] Specimens of fumarole minerals from Tolbachik and Kudryavy are hosted by the Fersman Mineralogical Museum in Moscow.[43]

Historical lava flows of Vesuvius volcano contain fumarolic minerals.[44] Various fumarole minerals have been discovered at Vulcano volcano in Italy, where the mineralogy has changed since 1987 and 1990 due to hotter fumarole exhalations,[45] yielding increased sulfate and sulfur salt concentrations.[46] Fumarolic minerals have also been encountered in multiple mud volcanoes in Siberia.[47]

Minerals discovered in fumarole areas

Mineral	Formula	Location	Date described	Ref
Abramovite	Pb 2SnInBiS 7	Kudryavy, Russia	2008	[48]
Allochalcoselite	Cu^+ Cu^2+ 5PbO 2(SeO 3) 2Cl 5			[49]
Aluminocoquimbite	AlFe(SO 4)^* 3H 2O	Grotta del' Alume, Vulcano, Italy	2010	[50]
Aluminopyracmonite	(NH 4) 3Al(SO 4) 3	La Fossa, Vulcano, Italy	2018	[51]
Arsmirandite	Na 18Cu^2+ 12Fe^3+ O 8(AsO 4) 8Cl 5	Arsenatnaya fumarole, Tolbachik, Russia	2020	[2]
Axelite	Na 14Cu 7(AsO 4) 8F 2Cl 2	Arsenatnaya fumarole, Tolbachik, Russia	2022	[52]
Baliczunicite	Bi 2O(SO 4) 2	La Fossa, Vulcano, Italy	2013	[46]
Belomarinaite	KNaSO 4	Toludskoe lava field, Tolbachik, Russia	2019	[53]
Belousovite	KZn(SO 4)Cl	Yadovitaya fumarole, Second Scoria Cone, Tolbachik, Russia	2018	[54]
Blossite	α‑Cu^2+ 2V^5+ 2O 7	Izalco, El Salvador	1987	[28]
Bubnovaite	K 2Na 8Ca(SO 4) 6	Naboko cone, Tolbachik, Russia		[55]
Burnsite	KCdCu 7O 2(SeO 3) 2Cl 9	Tolbachik	2002?	[56]
Cadmoindite	CdIn 2S 4	Kudryavy, Russia	2004	[57]
Calciolangbeinite	K 2Ca 2(SO 4) 3	Arsenatnaya fumarole, Tolbachik, Russia	2022	[58]
Campostriniite	(Bi^3+ ,Na) 3(NH^, 4K) 2Na 2(SO 4)^· 6H 2O	La Fossa, Vulcano, Italy	2015	[59]
Cannizzarite	Pb 46Bi 54(S ,Se) 127	La Fossa, Vulcano, Italy		[60]
Cesiodymite	CsKCu 5O(SO 4) 5	Second Scoria Cone, Tolbachik, Russia	2018	[61]
Chubarovite	KZn 2(BO 3)Cl 2	Arsenatnaya fumarole, Tolbachik, Russia	2015	[62]
Cryptocalcite	K 2Cu 5O(SO 4) 5	Second Scoria Cone, Tolbachik, Russia	2018	[61]
Cuprodobrovolskyite	Na 4Cu(SO 4) 3	Second Scoria Cone, Tolbachik	2023	[63]
Cupromolybdite	Cu 3O(MoO 4) 2	New Tolbachik scoria cones, Tolbachik, Russia	2012	[64]
D'ansite	Na 21Mn^2+ (SO 4) 10Cl	Vesuvius and Vulcano, Italy	2012	[65]
Demartinite	K 2SiF 6	La Fossa, Vulcano, Italy	2007	[66]
Demicheleite	BiSI and BiSBr	La Fossa, Vulcano, Italy	2010 and 2008	[67][68]
Dobrovolskyite	Na 4Ca(SO 4) 3	Great Tolbachik fissure eruption, Kamchatka peninsula, Russia	2021	[69]
Elasmochloite	Na 3Cu 6BiO 4(SO 4)			[70]
Eldfellite	NaFe(SO 4) 2			[71]
Ermakovite	(NH 4)(As 2O 3) 2Br	Fan-Yagnob coal deposit, Tajikistan	2022	[72]
Grigorievite	Cu 3Fe^3+ 2Al 2(VO 4)	Second Scoria Cone, Tolbachik, Russia	2015	[73]
Hermannjahnite	CuZn(SO 4) 2	Naboko scoria cone, Tolbachik, Russia	2018	[74]
Karpovite	Tl 2VO(SO 4) 2(H 2O)	First Cinder Cone, Tolbachik, Russia	2018	[75]
Knasibfite	K 3Na 4[SiF 6] 3[BF 4]	La Fossa, Vulcano, Italy	2008	[76]
Koksharovite	CaMg 2Fe^3+ 4(VO 4) 6	Bezymyanny, Russia	2015	[73]
Kristjánite	KNa 2H(SO 4) 2	Fimmvörðuháls, Iceland	2010	[77]
Kudriavite	(Cd ,Pb)Bi 2S 4	Kudryavy, Russia	2004	[57]
Lehmannite	Na 18Cu^2+ 12TiO 8(AsO 4) 8FCl 5	Arsenatnaya fumarole, Tolbachik	2020	[2]
Leonardsenite	MgAlF 5(H 2O) 2	Eldfell, Heimaey, Iceland	2015	[73]
Lesyukite	Al 2(OH) 5Cl^20− *H 2O	First Cone, Tolbachik, Russia	2007 or earlier	[78]
Lucabindiite	(K ,NH 4)As 4O 6(Cl ,Br)	La Fossa, Vulcano, Italy	2010–2011	[79]
Majzlanite	K 2Na(ZnNa)Ca(SO 4) 4	Yadovitaya fumarole, Tolbachik, Russia	2019	[80]
Manuelarossiite	CaPbAlF 7	Vesuvius volcano, Italy	2024?	[81]
Medvedevite	KMnV 2O 6Cl *(H 2O) 2	Toludskoe lava field, Tolbachik, Russia	2020	[82]
Napoliite	Pb 2OFCl	Vesuvius, 1994 rocks	2010-2020	[83]
Nishanbaevite	KAl 2O(AsO 4)(SO 4)	Arsenatnaya fumarole, Tolbachik, Russia	2022	[84]
Oskarssonite	AlF 3	Eldfell, Iceland	2018	[29]
Ozerovaite	Na 2KAl 3(AsO 4) 4	Second Cinder Cone, Tolbachik, Russia	2019	[85]
Paradimorphite	As 4S 3	Solfatara, Campi Flegrei, Italy	2022	[86]
Parageorgbokiite	^b- Cu 5O 2(SeO 3) 2Cl 2	Yadovitaya fumarole, Tolbachik, Russia	2007	[87]
Parascandolaite	KMgF 3	Vesuvius, Italy	2014	[88]
Parawulffite	K 5Na 3Cu 8O 4(SO 4) 8	Arsenatnaya fumarole, Tolbachik, Russia	2014	[89]
Petrovite	Na 10CaCu 2(SO 4) 8	Second Scoria Cone, Tolbachik, Russia	2020	[18]
Pliniusite	Ca 5(VO 4) 3F	Tolbachik, Russia	2022	[90]
Prewittite	KPb 1.5Cu 6Zn(SeO 3) 2O 2Cl 10	Second Scoria Cone, Tolbachik, Russia	2013	[39]
Pseudolyonsite	Cu 3(VO 4) 2	New Tolbachik scoria cones, Tolbachik, Russia	2011	[91]
Puninite	Na 2Cu 3O(SO 4) 3	Second scoria cone, Tolbachik, Russia	2017	[92]
Rhabdoborite	Mg 12(V ,Mo ,W) 4/3O 6[(BO 3) 6–x(PO 4) xF 2–x]	Arsenatnaya fumarole, Tolbachik, Russia	2020	[93]
Russoite	NH 4ClAs^3+ 2O 3(H 2O) 0.5	Solfatara, Phlegrean Fields, Italy	2018	[94]
Ryabchikovite	CuMg(Si 2O 6)	Arsenatnaya, Tolbachik	2023	[95]
Sbacchiite	Ca 2AlF 7	Vesuvius, Italy	2019	[96]
Shcherbinaite	V 2O 5	Izalco, El Salvador	1983	[97]
Stoiberite	Cu 5V 2O 10	"Y fumarole", Izalco, El Salvador	1979	[98]
Therasiaite	(NH 4) 3KNa 2Fe^2+ Fe^3+ (SO 4) 3Cl 5	La Fossa, Vulcano, Italy	2014	[99]
Thermessaite	(NH 4) 2AlF 3(SO 4)	La Fossa, Vulcano, Italy	2021	[100]
Topsøeite	FeF 3(H 2O) 3	Hekla, Iceland	2018	[101]
Wulffite	K 3NaCu 4O 2(SO 4) 4	Arsenatnaya fumarole, Tolbachik, Russia	2014	[89]
Vasilseverginite	Cu 9O 4(AsO 4) 2(SO 4) 2	Arsenatnaya fumarole, Tolbachik, Russia	2021	[102]
Wrightite	K 2Al 2O(AsO 4) 2	Second Scoria Cone, Tolbachik, Russia	1983	[103]
Yavapaiite	KFe(SO 4) 2			[71]
Ziminaite	Fe^3+ VO 4	Bezymyanny, Russia	2018	[104]
Zincobradaczekite	NaCuCuZn 2(AsO 4) 3	Yadovitaya fumarole, Tolbachik, Russia	2020	[105]

Gallery

• Scanning electron microscope images of fumarole minerals
• 
  Fumarole minerals in natural colours
• 
  Fumarole minerals in natural colours, Mutnovsky, Kamchatka
• 
  Fumarole minerals in natural colours, Tolbachik, Kamchatka

• Photos of fumarole minerals
• 
  Non-SEM photo of belomarinaite from Tolbachik, Kamchatka

References

1. Manahan, Stanley E. (26 August 2004). Environmental Chemistry (Eighth ed.). CRC Press. p. 408. ISBN 978-1-56670-633-9.
2. Britvin et al. 2020, p. 2.
3. Ganino, Libourel & Bernard 2019, p. 75.
4. Stracher et al. 2005, p. 1736.
5. Stoiber & Rose 1974, p. 513.
6. Kodosky & Keith 1993, p. 185.
7. Stoiber & Rose 1974, p. 514.
8. Renggli & Klemme 2020, p. 1.
9. Shevko, E. P.; Bortnikova, S. B.; Abrosimova, N. A.; Kamenetsky, V. S.; Bortnikova, S. P.; Panin, G. L.; Zelenski, M. (20 March 2018). "Trace Elements and Minerals in Fumarolic Sulfur: The Case of Ebeko Volcano, Kuriles". Geofluids. 2018: 1–16. doi:10.1155/2018/4586363.
10. Guy et al. 2020, p. 466.
11. Kuenzer, Claudia; Stracher, Glenn B. (1 February 2012). "Geomorphology of coal seam fires". Geomorphology. 138 (1): 217. Bibcode:2012Geomo.138..209K. doi:10.1016/j.geomorph.2011.09.004. ISSN 0169-555X.
12. Stracher et al. 2005, p. 1738.
13. Yen, A. S.; Morris, R. V.; Clark, B. C.; Gellert, R.; Knudson, A. T.; Squyres, S.; Mittlefehldt, D. W.; Ming, D. W.; Arvidson, R.; McCoy, T.; Schmidt, M.; Hurowitz, J.; Li, R.; Johnson, J. R. (2008). "Hydrothermal processes at Gusev Crater: An evaluation of Paso Robles class soils". Journal of Geophysical Research: Planets. 113 (E6): 16. Bibcode:2008JGRE..113.6S10Y. doi:10.1029/2007JE002978. ISSN 2156-2202.
14. Jin, Shifeng; Hao, Munan; Guo, Zhongnan; Yin, Bohao; Ma, Yuxin; Deng, Lijun; Chen, Xu; Song, Yanpeng; Cao, Cheng; Chai, Congcong; Wei, Qi; Ma, Yunqi; Guo, Jiangang; Chen, Xiaolong (16 July 2024). "Evidence of a hydrated mineral enriched in water and ammonium molecules in the Chang'e-5 lunar sample". Nature Astronomy. 8 (9): 5. arXiv:2305.05263. Bibcode:2024NatAs...8.1127J. doi:10.1038/s41550-024-02306-8.
15. Keith 1991, p. 236.
16. Kodosky & Keith 1993, p. 187.
17. Pekov, Igor V.; Britvin, Sergey N.; Agakhanov, Atali A.; Vigasina, Marina F.; Sidorov, Evgeny G. (1 September 2019). "Elasmochloite, Na₃Cu₆BiO₄(SO₄)₅, a new fumarolic mineral from the Tolbachik volcano, Kamchatka, Russia". European Journal of Mineralogy. 31 (5–6): 1026. Bibcode:2019EJMin..31.1025P. doi:10.1127/ejm/2019/0031-2887. ISSN 0935-1221. S2CID 213388684.
18. Filatov, Stanislav K.; Shablinskii, Andrey P.; Krivovichev, Sergey V.; Vergasova, Lidiya P.; Moskaleva, Svetlana V. (2020). "Petrovite, Na₁₀CaCu₂(SO₄)₈, a new fumarolic sulfate from the Great Tolbachik fissure eruption, Kamchatka Peninsula, Russia". Mineralogical Magazine. 84 (5): 691–698. Bibcode:2020MinM...84..691F. doi:10.1180/mgm.2020.53. ISSN 0026-461X. S2CID 225662607.
19. Shchipalkina et al. 2020, p. 101.
20. Stoiber & Rose 1974, p. 496.
21. Borisov et al. 2024, p. 2.
22. Gazis, Carey; Taylor, Hugh P.; Hon, Ken; Tsvetkov, Andrei (1 October 1996). "Oxygen isotopic and geochemical evidence for a short-lived, high-temperature hydrothermal event in the Chegem caldera, Caucasus Mountains, Russia". Journal of Volcanology and Geothermal Research. 73 (3): 241. Bibcode:1996JVGR...73..213G. doi:10.1016/0377-0273(96)00023-6. ISSN 0377-0273. Archived from the original on 28 June 2024. Retrieved 31 December 2020.
23. Holt, Elizabeth Warner; Taylor, Hugh P. (1 July 1998). "18O/16O mapping and hydrogeology of a short-lived (≈10 years) fumarolic (>500 °C) meteoric–hydrothermal event in the upper part of the 0.76 Ma Bishop Tuff outflow sheet, California1Contribution No. 8478, Division of Geological and Planetary Sciences, Caltech.1". Journal of Volcanology and Geothermal Research. 83 (1): 135. doi:10.1016/S0377-0273(98)00014-6. ISSN 0377-0273.
24. Keith 1991, p. 230.
25. Hazen, Robert M.; Ausubel, Jesse H. (1 June 2016). "On the nature and significance of rarity in mineralogy". American Mineralogist. 101 (6): 1247. Bibcode:2016AmMin.101.1245H. doi:10.2138/am-2016-5601CCBY. ISSN 0003-004X. S2CID 9906353.
26. Pekov et al. 2018, p. 306.
27. Ganino, Libourel & Bernard 2019, p. 85.
28. Robinson, Paul D.; Hughes, John M.; Malinconico, MaryAnn L. (1 April 1987). "Blossite, α-Cu^2+
    ₂V^5+
    ₂O₇, a new fumarolic sublimate from Izalco Volcano, El Salvador". American Mineralogist. 72 (3–4): 397–399. ISSN 0003-004X. Archived from the original on 18 August 2021. Retrieved 12 December 2020.
29. Jacobsen, M. J.; Balić -Žunić, T.; Mitolo, D.; Katerinopoulou, A.; Garavelli, A.; Jakobsson, S. P. (2018). "Oskarssonite, AlF₃, a new fumarolic mineral from Eldfell volcano, Heimaey, Iceland". Mineralogical Magazine. 78 (1): 215–216. doi:10.1180/minmag.2014.078.1.15. ISSN 0026-461X. S2CID 131738318. Archived from the original on 2021-01-15. Retrieved 2020-12-12.
30. FRANZA, ANNARITA; PETTI, CARMELA; PRATESI, GIOVANNI (20 April 2021). "MORE THAN JUST A ROCK COLLECTION. THE METEORITE COLLECTION OF THE ITALIAN GEOLOGIST TEODORO MONTICELLI (1759–1845)". Earth Sciences History. 40 (1): 46. Bibcode:2021ESHis..40...39F. doi:10.17704/1944-6187-40.1.39. ISSN 0736-623X. S2CID 234963797. Archived from the original on 8 December 2021. Retrieved 10 December 2021.
31. Inostroza, Manuel; Aguilera, Felipe; Menzies, Andrew; Layana, Susana; González, Cristóbal; Ureta, Gabriel; Sepúlveda, José; Scheller, Samuel; Böehm, Stephan; Barraza, María; Tagle, Roald; Patzschke, Max (1 March 2020). "Deposition of metals and metalloids in the fumarolic fields of Guallatiri and Lastarria volcanoes, northern Chile". Journal of Volcanology and Geothermal Research. 393: 13. Bibcode:2020JVGR..39306803I. doi:10.1016/j.jvolgeores.2020.106803. ISSN 0377-0273. S2CID 212875067.
32. Yudovskaya et al. 2006, p. 828.
33. Yudovskaya et al. 2006, p. 837.
34. Adams, Paul M.; Lynch, David K.; Buckland, Kerry N.; Johnson, Patrick D.; Tratt, David M. (15 November 2017). "Sulfate mineralogy of fumaroles in the Salton Sea Geothermal Field, Imperial County, California". Journal of Volcanology and Geothermal Research. 347: 41. Bibcode:2017JVGR..347...15A. doi:10.1016/j.jvolgeores.2017.08.010. ISSN 0377-0273.
35. Petrov, Alfredo; Smith, Bill; Smith, Carol (1 November 2001). "A Guide to Mineral Localities in Bolivia". The Mineralogical Record. 32 (6): 2. Archived from the original on 30 October 2023. Retrieved 13 December 2020.
36. Drummond, Carl N. (August 2024). "Abundances, distributions and patterns of discovery of new minerals". Mineralogical Magazine. 88 (4): 422. Bibcode:2024MinM...88..421D. doi:10.1180/mgm.2024.19.
37. Pekov et al. 2018, p. 318.
38. Shchipalkina et al. 2020, p. 102.
39. Shuvalov, Robert R.; Vergasova, Lidiya P.; Semenova, Tatyana F.; Filatov, Stanislav K.; Krivovichev, Sergey V.; Siidra, Oleg I.; Rudashevsky, Nikolay S. (1 February 2013). "Prewittite, KPb_1.5Cu₆Zn(SeO₃)₂O₂Cl₁₀, a new mineral from Tolbachik fumaroles, Kamchatka peninsula, Russia: Description and crystal structure". American Mineralogist. 98 (2–3): 463. Bibcode:2013AmMin..98..463S. doi:10.2138/am.2013.4174. ISSN 1945-3027. S2CID 102031214.
40. Sergeeva, A. V.; Zhitova, E. S.; Nuzhdaev, A. A.; Nazarova, M. A. (1 February 2022). "Modeling the Process of Mineral Generation in Thermal Anomalies with Ammonium Sulfate Thermal Waters: The Role of рН". Journal of Volcanology and Seismology. 16 (1): 35. doi:10.1134/S0742046321060099. ISSN 1819-7108. S2CID 247749830. Archived from the original on 2 November 2022. Retrieved 2 November 2022.
41. Shchipalkina et al. 2020, p. 103.
42. Kamenetsky, Vadim S.; Belousov, Alexander; Sharygin, Victor V.; Zhitova, Liudmila M.; Ehrig, Kathy; Zelenski, Michael E.; Chaplygin, Ilya; Yudovskaya, Marina A.; Nesterenko, Pavel N.; Zakharov, Sergey M. (December 2019). "High-temperature gold-copper extraction with chloride flux in lava tubes of Tolbachik volcano (Kamchatka)" (PDF). Terra Nova. 31 (6): 515. Bibcode:2019TeNov..31..511K. doi:10.1111/ter.12420. S2CID 200032791. Archived (PDF) from the original on 2020-10-22. Retrieved 2020-12-31.
43. Robinson, George W.; Scovil, Jeffrey; King, Vandall T.; Cureton, Forrest (1 September 1995). "World review of mineral discoveries: 1993–1994". The Mineralogical Record. 26 (5): 13. Archived from the original on 30 October 2023. Retrieved 13 December 2020.
44. Voltaggio, Mario; Branca, Marilì; Tedesco, Dario; Tuccimei, Paola; Di Pietro, Laura (1 January 2004). "^226Ra-excess during the 1631–1944 activity period of Vesuvius (Italy): A model of alpha-recoil enrichment in a metasomatized mantle and implications on the current state of the magmatic system". Geochimica et Cosmochimica Acta. 68 (1): 175. Bibcode:2004GeCoA..68..167V. doi:10.1016/S0016-7037(03)00236-9. ISSN 0016-7037.
45. Pinto, Garavelli & Mitolo 2014, p. 1.
46. Pinto, Garavelli & Mitolo 2014, p. 2.
47. Tatarinov, A. V.; Yalovik, L. I.; Kanakin, S. V. (1 July 2016). "The generation and mineral associations of rock assemblages at mud volcanoes: Southeastern Siberia". Journal of Volcanology and Seismology. 10 (4): 254. Bibcode:2016JVolS..10..248T. doi:10.1134/S0742046316030052. ISSN 1819-7108. S2CID 132970719.
48. Yudovskaya, M. A.; Trubkin, N. V.; Koporulina, E. V.; Belakovsky, D. I.; Mokhov, A. V.; Kuznetsova, M. V.; Golovanova, T. I. (1 December 2008). "Abramovite, Pb₂SnInBiS₇, a new mineral species from fumaroles of the Kudryavy volcano, Kurile Islands, Russia". Geology of Ore Deposits. 50 (7): 551. Bibcode:2008GeoOD..50..551Y. doi:10.1134/S1075701508070052. ISSN 1555-6476. S2CID 140650406. Archived from the original on 24 October 2022. Retrieved 6 December 2020.
49. Lykova, Inna; Rowe, Ralph; Poirier, Glenn; Friis, Henrik; Helwig, Kate (9 December 2022). "Bounahasite, Cu^+Cu^2+₂(OH)₃Cl₂, a new mineral from the Bou Nahas Mine, Morocco". Mineralogical Magazine. 87 (2): 218–224. doi:10.1180/mgm.2022.133. hdl:10852/101312. S2CID 254532654.
50. Demartin, Francesco; Castellano, Carlo; Gramaccioli, Carlo Maria; Campostrini, Italo (1 December 2010). "ALUMINOCOQUIMBITE, AlFe(SO₄)₃·9H₂O, A NEW ALUMINUM IRON SULFATE FROM GROTTA DELL'ALLUME, VULCANO, AEOLIAN ISLANDS, ITALY". The Canadian Mineralogist. 48 (6): 1465. doi:10.3749/canmin.48.5.1465. ISSN 0008-4476.
51. Demartin, F.; Castellano, C.; Campostrini, I. (2018). "Aluminopyracmonite, (NH₄)₃Al(SO₄)₃, a new ammonium aluminium sulfate from La Fossa crater, Vulcano, Aeolian Islands, Italy". Mineralogical Magazine. 77 (4): 443. doi:10.1180/minmag.2013.077.4.04. ISSN 0026-461X. S2CID 130573127. Archived from the original on 2021-08-18. Retrieved 2020-12-06.
52. Pekov, Igor V.; Zubkova, Natalia V.; Agakhanov, Atali A.; Yapaskurt, Vasiliy O.; Belakovskiy, Dmitry I.; Britvin, Sergey N.; Sidorov, Evgeny G.; Kutyrev, Anton V.; Pushcharovsky, Dmitry Yu (2022). "New arsenate minerals from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. XIX. Axelite, Na₁₄Cu₇(AsO₄)₈F₂Cl₂". Mineralogical Magazine. 87: 109–117. doi:10.1180/mgm.2022.120. ISSN 0026-461X. S2CID 253787792.
53. Filatov, Stanislav K.; Shablinskii, Andrey P.; Vergasova, Lidiya P.; Saprikina, Olga U.; Bubnova, Rimma S.; Moskaleva, Svetlana V.; Belousov, Alexander B. (2019). "Belomarinaite KNa(SO₄): A new sulfate from 2012–2013 Tolbachik Fissure eruption, Kamchatka Peninsula, Russia". Mineralogical Magazine. 83 (4): 569–575. Bibcode:2019MinM...83..569F. doi:10.1180/mgm.2018.170. ISSN 0026-461X. S2CID 133750327.
54. Siidra, Oleg I.; Nazarchuk, Evgeny V.; Lukina, Evgeniya A.; Zaitsev, Anatoly N.; Shilovskikh, Vladimir V. (2018). "Belousovite, KZn(SO₄)Cl, a new sulfate mineral from the Tolbachik volcano with apophyllite sheet-topology". Mineralogical Magazine. 82 (5): 1079–1080. Bibcode:2018MinM...82.1079S. doi:10.1180/minmag.2017.081.084. ISSN 0026-461X. S2CID 133993574.
55. Gorelova, Liudmila A.; Vergasova, Lidiya P.; Krivovichev, Sergey V.; Avdontseva, Evgenia Yu; Moskaleva, Svetlana V.; Karpov, Genadii A.; Filatov, Stanislav K. (1 June 2016). "Bubnovaite, K₂Na₈Ca(SO₄)₆, a new mineral species with modular structure from the Tolbachik volcano, Kamchatka peninsula, Russia". European Journal of Mineralogy. 28 (3): 677. Bibcode:2016EJMin..28..677G. doi:10.1127/ejm/2016/0028-2530. ISSN 0935-1221.
56. Borisov et al. 2024, p. 16.
57. Yudovskaya et al. 2006, p. 830.
58. Pekov, Igor V.; Zubkova, Natalia V.; Galuskina, Irina O.; Kusz, Joachim; Koshlyakova, Natalia N.; Galuskin, Evgeny V.; Belakovskiy, Dmitry I.; Bulakh, Maria O.; Vigasina, Marina F.; Chukanov, Nikita V.; Britvin, Sergey N.; Sidorov, Evgeny G.; Vapnik, Yevgeny; Pushcharovsky, Dmitry Yu. (August 2022). "Calciolangbeinite- O, a natural orthorhombic modification of K₂Ca₂(SO₄)₃, and the langbeinite–calciolangbeinite solid-solution system". Mineralogical Magazine. 86 (4): 557–569. Bibcode:2022MinM...86..557P. doi:10.1180/mgm.2021.95. S2CID 246406414.
59. Demartin, Francesco; Castellano, Carlo; Gramaccioli, Carlo Maria (2015). "Campostriniite, (Bi^3+,Na)₃(NH₄,K)₂Na₂(SO₄)₆·H₂O, a new sulfate isostructural with görgeyite, from La Fossa Crater, Vulcano, Aeolian Islands, Italy". Mineralogical Magazine. 79 (4): 1007–1008. Bibcode:2015MinM...79.1007D. doi:10.1180/minmag.2015.079.4.10. ISSN 0026-461X. S2CID 130849371. Archived from the original on 2021-08-18. Retrieved 2020-12-12.
60. Topa, Dan; Makovicky, Emil; Dittrich, Herbert (1 June 2010). "The Crystal Structure of 7H:12Q Cannizzarite from Vulcano, Italy". The Canadian Mineralogist. 48 (3): 484. Bibcode:2010CaMin..48..483T. doi:10.3749/canmin.48.3.483. ISSN 0008-4476. Archived from the original on 28 June 2024. Retrieved 5 December 2020.
61. Pekov, Igor V.; Zubkova, Natalia V.; Agakhanov, Atali A.; Pushcharovsky, Dmitry Y.; Yapaskurt, Vasiliy O.; Belakovskiy, Dmitry I.; Vigasina, Marina F.; Sidorov, Evgeny G.; Britvin, Sergey N. (1 May 2018). "Cryptochalcite, K₂Cu₅O(SO₄)₅, and cesiodymite, CsKCu5O(SO4)5, two new isotypic minerals and the K–Cs isomorphism in this solid-solution series". European Journal of Mineralogy. 30 (3): 593. Bibcode:2018EJMin..30..593P. doi:10.1127/ejm/2018/0030-2725. ISSN 0935-1221. S2CID 135272395.
62. Pekov, Igor V.; Zubkova, Natalia V.; Pautov, Leonid A.; Yapaskurt, Vasiliy O.; Chukanov, Nikita V.; Lykova, Inna S.; Britvin, Sergey N.; Sidorov, Evgeny G.; Pushcharovsky, Dmitry Yu (1 March 2015). "CHUBAROVITE, KZn₂(BO₃)Cl₂, A NEW MINERAL SPECIES FROM THE TOLBACHIK VOLCANO, KAMCHATKA, RUSSIATHE CANADIAN MINERALOGIST". The Canadian Mineralogist. 53 (2): 273. doi:10.3749/canmin.1400080. ISSN 0008-4476.
63. Shchipalkina, Nadezhda V.; Pekov, Igor V.; Koshlyakova, Natalia N.; Belakovskiy, Dmitry I.; Zubkova, Natalia V.; Agakhanov, Atali A.; Britvin, Sergey N.; Nazarova, Maria A. (13 November 2023). "A new mineral cuprodobrovolskyite Na4Cu(SO4)3 from the Tolbachik volcano (Kamchatka, Russia) and the relations in the family of natural anhydrous Na-Cu sulfates". Mineralogical Magazine: 1–32. doi:10.1180/mgm.2023.85. ISSN 0026-461X.
64. Zelenski, Michael E.; Zubkova, Natalia V.; Pekov, Igor V.; Polekhovsky, Yuri S.; Pushcharovsky, Dmitry Yu (1 August 2012). "Cupromolybdite, Cu₃O(MoO₄)₂, a new fumarolic mineral from the Tolbachik volcano, Kamchatka Peninsula, Russia". European Journal of Mineralogy. 24 (4): 750. Bibcode:2012EJMin..24..749Z. doi:10.1127/0935-1221/2012/0024-2221. ISSN 0935-1221.
65. Demartin, F.; Campostrini, I.; Castellano, C.; Gramaccioli, C. M.; Russo, M. (1 December 2012). "D'ansite-(Mn), Na₂₁Mn^2+(SO₄)₁₀Cl₃ and d'ansite-(Fe), Na₂₁Fe^2+(SO₄)₁₀Cl₃, two new minerals from volcanic fumaroles". Mineralogical Magazine. 76 (7): 2773–2774. Bibcode:2012MinM...76.2773D. doi:10.1180/minmag.2012.076.7.10. ISSN 0026-461X. S2CID 93766296. Archived from the original on 30 October 2023. Retrieved 12 December 2020.
66. Gramaccioli, Carlo Maria; Campostrini, Italo (1 October 2007). "DEMARTINITE, A NEW POLYMORPH OF K₂SiF₆ FROM LA FOSSA CRATER, VULCANO, AEOLIAN ISLANDS, ITALY". The Canadian Mineralogist. 45 (5): 1275. Bibcode:2007CaMin..45.1275G. doi:10.2113/gscanmin.45.5.1275. ISSN 0008-4476.
67. Demartin, Francesco; Gramaccioli, Carlo Maria; Campostrini, Italo; Orlandi, Paolo (1 October 2008). "Demicheleite, BiSBr, a new mineral from La Fossa crater, Vulcano, Aeolian Islands, Italy". American Mineralogist. 93 (10): 1603–1604. Bibcode:2008AmMin..93.1603D. doi:10.2138/am.2008.2883. ISSN 0003-004X. S2CID 56410190. Archived from the original on 2 June 2018. Retrieved 12 December 2020.
68. Demartin, F.; Gramaccioli, C. M.; Campostrini, I. (2010). "Demicheleite-(I), BiSI, a new mineral from La Fossa Crater, Vulcano, Aeolian Islands, Italy". Mineralogical Magazine. 74 (1): 141–142. Bibcode:2010MinM...74..141D. doi:10.1180/minmag.2010.074.1.141. ISSN 0026-461X. S2CID 129827579. Archived from the original on 2023-10-30. Retrieved 2020-12-12.
69. Shablinskii, Andrey P.; Filatov, Stanislav K.; Krivovichev, Sergey V.; Vergasova, Lidiya P.; Moskaleva, Svetlana V.; Avdontseva, Eugeniya Yu; Knyazev, Alexander V.; Bubnova, Rimma S. (April 2021). "Dobrovolskyite, Na₄Ca(SO₄)₃, a new fumarolic sulfate from the Great Tolbachik fissure eruption, Kamchatka Peninsula, Russia". Mineralogical Magazine. 85 (2): 233–241. Bibcode:2021MinM...85..233S. doi:10.1180/mgm.2021.9. ISSN 0026-461X. S2CID 233260565. Archived from the original on 2021-02-02. Retrieved 2021-12-08.
70. Yakubovich, Olga V.; Shvanskaya, Larisa V.; Kiriukhina, Galina V.; Volkov, Anatoly S.; Dimitrova, Olga V.; Vasiliev, Alexander N. (2 August 2021). "Hydrothermal Synthesis and a Composite Crystal Structure of Na₆Cu₇BiO₄(PO₄)₄[Cl,(OH)]₃ as a Candidate for Quantum Spin Liquid". Inorganic Chemistry. 60 (15): 11455. doi:10.1021/acs.inorgchem.1c01459. ISSN 0020-1669. PMID 34264636. S2CID 235961251. Archived from the original on 8 December 2021. Retrieved 8 December 2021.
71. Singh, Shashwat; Singh, Deobrat; Ahuja, Rajeev; Fichtner, Maximilian; Barpanda, Prabeer (2023). "Eldfellite NaV(SO 4 ) 2 as a versatile cathode insertion host for Li-ion and Na-ion batteries". Journal of Materials Chemistry A. 11 (8): 3975–3986. doi:10.1039/D2TA03673H. S2CID 252422867. Archived from the original on 2022-12-18. Retrieved 2022-12-18.
72. Karpenko, Vladimir Yu.; Pautov, Leonid A.; Siidra, Oleg I.; Mirakov, Mirak A.; Zaitsev, Anatoly N.; Plechov, Pavel Yu.; Makhmadsharif, Saimudasir (14 October 2022). "Ermakovite (NH₄)(As₂O₃)₂Br, a new exhalative arsenite bromide mineral from the Fan-Yagnob coal deposit, Tajikistan". Mineralogical Magazine. 87: 69–78. doi:10.1180/mgm.2022.116. S2CID 252906686.
73. Cámara, Gagne & Uvarova 2015, p. 660.
74. Siidra, Oleg I.; Nazarchuk, Evgeny V.; Agakhanov, Atali A.; Lukina, Evgeniya A.; Zaitsev, Anatoly N.; Turner, Rick; Filatov, Stanislav K.; Pekov, Igor V.; Karpov, Gennady A.; Yapaskurt, Vasiliy O. (1 February 2018). "Hermannjahnite, CuZn(SO₄)₂, a new mineral with chalcocyanite derivative structure from the Naboko scoria cone of the 2012–2013 fissure eruption at Tolbachik volcano, Kamchatka, Russia". Mineralogy and Petrology. 112 (1): 123. Bibcode:2018MinPe.112..123S. doi:10.1007/s00710-017-0520-4. ISSN 1438-1168. S2CID 134441203. Archived from the original on 15 June 2018. Retrieved 6 December 2020.
75. Siidra, Oleg I.; Vergasova, Lidiya P.; Kretser, Yuri L.; Polekhovsky, Yuri S.; Filatov, Stanislav K.; Krivovichev, Sergey V. (2018). "Unique thallium mineralization in the fumaroles of the Tolbachik volcano, Kamchatka Peninsula, Russia. II. Karpovite, Tl₂VO(SO₄)₂(H₂O)". Mineralogical Magazine. 78 (7): 1699–1700. doi:10.1180/minmag.2014.078.7.13. ISSN 0026-461X. S2CID 131377092. Archived from the original on 2022-05-04. Retrieved 2020-12-12.
76. Demartin, Francesco; Gramaccioli, Carlo Maria; Campostrini, Italo; Orlandi, Paolo (1 April 2008). "KNASIBFITE, K₃Na₄[SiF₆]₃[BF₄], A NEW HEXAFLUOROSILICATE–TETRAFLUOROBORATE FROM LA FOSSA CRATER, VULCANO, AEOLIAN ISLANDS, ITALY". The Canadian Mineralogist. 46 (2): 447. Bibcode:2008CaMin..46..447D. doi:10.3749/canmin.46.2.447. ISSN 0008-4476.
77. Balić-Žunić, Tonči; Nestola, Fabrizio; Pamato, Martha G.; Rasmussen, Maja B. (June 2024). "Kristjánite, KNa2H(SO4)2, a new fumarolic mineral from Iceland containing the [SO4–H–SO4]3– anion in the crystal structure". Mineralogical Magazine. 88 (3): 211–217. Bibcode:2024MinM...88..211B. doi:10.1180/mgm.2024.4. hdl:11577/3513042. ISSN 0026-461X.
78. Vergasova, Filatov & Dunin-Barkovskaya 2007, p. 131.
79. Garavelli, Anna; Mitolo, Donatella; Pinto, Daniela; Vurro, Filippo (1 February 2013). "Lucabindiite, (K,NH₄)As₄O₆(Cl,Br), a new fumarole mineral from the "La Fossa" crater at Vulcano, Aeolian Islands, Italy". American Mineralogist. 98 (2–3): 470–477. Bibcode:2013AmMin..98..470G. doi:10.2138/am.2013.4194. ISSN 0003-004X. S2CID 101028046. Archived from the original on 28 June 2024. Retrieved 5 December 2020 – via ResearchGate.
80. Siidra, Oleg I.; Nazarchuk, Evgeny V.; Zaitsev, Anatoly N.; Shilovskikh, Vladimir V. (2019). "Majzlanite, K₂Na(ZnNa)Ca(SO₄)₄, a new anhydrous sulfate mineral with complex cation substitutions from Tolbachik volcano". Mineralogical Magazine. 84 (1): 153–158. doi:10.1180/mgm.2019.68. ISSN 0026-461X. S2CID 210610798. Archived from the original on 2020-03-09. Retrieved 2020-12-06.
81. Nestola, Fabrizio; Kasatkin, Anatoly V.; Biagioni, Cristian; Gurzhiy, Vladislav V.; Škoda, Radek; Santello, Lisa; Agakhanov, Atali A. (11 November 2024). "Manuelarossiite, CaPbAlF7, a new fluoride from the Vesuvius volcano, Italy". Mineralogical Magazine: 1–20. doi:10.1180/mgm.2024.59. ISSN 0026-461X.
82. Shablinskii, Andrey P.; Avdontceva, Margarita S.; Vergasova, Lidiya P.; Filatov, Stanislav K.; Avdontseva, Evgenia Yu.; Povolotskiy, Alexey V.; Moskaleva, Svetlana V.; Kargopoltsev, Anatoly A.; Britvin, Sergey N.; Shorets, Olga U. (June 2022). "Medvedevite, KMn^2+V^5+₂O₆Cl⋅2H₂O, a new fumarolic mineral from the Tolbachik fissure eruption 2012–2013, Kamchatka Peninsula, Russia". Mineralogical Magazine. 86 (3): 478–485. doi:10.1180/mgm.2022.38. S2CID 248781337.
83. Kasatkin, Anatoly V.; Siidra, Oleg I.; Nestola, Fabrizio; Pekov, Igor V.; Agakhanov, Atali A.; Koshlyakova, Natalia N.; Chukanov, Nikita V.; Nazarchuk, Evgeny V.; Molinari, Simone; Rossi, Manuela (October 2023). "Napoliite, Pb 2 OFCl, a new mineral from Vesuvius volcano, and its relationship with dimorphous rumseyite". Mineralogical Magazine. 87 (5): 711–718. Bibcode:2023MinM...87..711K. doi:10.1180/mgm.2023.43.
84. Pekov, Igor V.; Zubkova, Natalia V.; Yapaskurt, Vasiliy O.; Belakovskiy, Dmitry I.; Britvin, Sergey N.; Agakhanov, Atali A.; Turchkova, Anna G.; Sidorov, Evgeny G.; Kutyrev, Anton V.; Blatov, Vladislav A.; Pushcharovsky, Dmitry Y. (9 December 2022). "Nishanbaevite, KAl₂O(AsO₄)(SO₄), a new As/S-ordered arsenate-sulfate mineral of fumarolic origin". Mineralogy and Petrology. 117 (2): 247–257. Bibcode:2023MinPe.117..247P. doi:10.1007/s00710-022-00803-0. ISSN 1438-1168. S2CID 254533626. Archived from the original on 16 December 2022. Retrieved 16 December 2022.
85. Shablinskii, Andrey P.; Filatov, Stanislav K.; Vergasova, Lidiya P.; Avdontseva, Eugeniya YU; Moskaleva, Svetlana V.; Povolotskiy, Aleksey V. (1 January 2019). "Ozerovaite, Na₂KAl₃(AsO₄)₄, new mineral species from Tolbachik volcano, Kamchatka peninsula, Russia". European Journal of Mineralogy. 31 (1): 159. Bibcode:2019EJMin..31..159S. doi:10.1127/ejm/2019/0031-2808. ISSN 0935-1221. S2CID 134630812.
86. Campostrini, Italo; Castellano, Carlo; Demartin, Francesco; Rocchetti, Ivano; Russo, Massimo; Vignola, Pietro (June 2022). "Paradimorphite, β-As₄S₃, a vintage new mineral from Solfatara di Pozzuoli and Vesuvius, Napoli, Italy". Mineralogical Magazine. 86 (3): 500–506. doi:10.1180/mgm.2022.47. hdl:2434/939089. S2CID 248765374.
87. Krivovichev, Sergey V.; Filatov, Stanislav K.; Burns, Peter C.; Vergasova, Lidiya P. (1 August 2007). "THE CRYSTAL STRUCTURE OF PARAGEORGBOKIITE, β-Cu₅O₂(SeO₃)₂Cl₂". The Canadian Mineralogist. 45 (4): 929. Bibcode:2007CaMin..45..929K. doi:10.2113/gscanmin.45.4.929. ISSN 0008-4476.
88. Demartin, Francesco; Campostrini, Italo; Castellano, Carlo; Russo, Massimo (1 June 2014). "Parascandolaite, KMgF₃, a new perovskite-type fluoride from Vesuvius". Physics and Chemistry of Minerals. 41 (6): 403. Bibcode:2014PCM....41..403D. doi:10.1007/s00269-014-0668-y. ISSN 1432-2021. S2CID 95302985. Archived from the original on 16 June 2018. Retrieved 6 December 2020.
89. Pekov, Igor V.; Zubkova, Natalia V.; Yapaskurt, Vasiliy O.; Belakovskiy, Dmitry I.; Chukanov, Nikita V.; Lykova, Inna S.; Savelyev, Dmitry P.; Sidorov, Evgeny G.; Pushcharovsky, Dmitry Yu (1 August 2014). "Wulffite, K₃NaCu₄O₂(SO₄)₄, and Parawulffite, K₅Na₃Cu₈O₄(SO₄)₈, Two New Minerals from Fumarole Sublimates of the Tolbachik Volcano, Kamchatka, Russia". The Canadian Mineralogist. 52 (4): 699. Bibcode:2014CaMin..52..699P. doi:10.3749/canmin.1400018. ISSN 0008-4476.
90. Pekov, Igor V.; Koshlyakova, Natalia N.; Zubkova, Natalia V.; Krzątała, Arkadiusz; Belakovskiy, Dmitry I.; Galuskina, Irina O.; Galuskin, Evgeny V.; Britvin, Sergey N.; Sidorov, Evgeny G.; Vapnik, Yevgeny; Pushcharovsky, Dmitry Yu (1 August 2022). "Pliniusite, Ca₅(VO₄)₃F, a new apatite-group mineral and the novel natural ternary solid-solution system pliniusite–svabite–fluorapatite". American Mineralogist. 107 (8): 1626–1634. doi:10.2138/am-2022-8100. S2CID 251071645. Archived from the original on 2 November 2022. Retrieved 2 November 2022.
91. Zelenski, Michael E.; Zubkova, Natalia V.; Pekov, Igor V.; Boldyreva, Maya M.; Pushcharovsky, Dmitry YU; Nekrasov, Aleksey N. (1 June 2011). "Pseudolyonsite, Cu₃(VO₄)₂, a new mineral species from the Tolbachik volcano, Kamchatka Peninsula, Russia". European Journal of Mineralogy. 23 (3): 475. Bibcode:2011EJMin..23..475Z. doi:10.1127/0935-1221/2011/0023-2101. ISSN 0935-1221.
92. Siidra, Oleg I.; Nazarchuk, Evgenii V.; Zaitsev, Anatoly N.; Lukina, Evgeniya A.; Avdontseva, Evgeniya Y.; Vergasova, Lidiya P.; Vlasenko, Natalia S.; Filatov, Stanislav K.; Turner, Rick; Karpov, Gennady A. (1 June 2017). "Copper oxosulphates from fumaroles of Tolbachik volcano: puninite, Na₂Cu₃O(SO₄)₃ –a new mineral species and structure refinements of kamchatkite and alumoklyuchevskite". European Journal of Mineralogy. 29 (3): 499–510. Bibcode:2017EJMin..29..499S. doi:10.1127/ejm/2017/0029-2619. ISSN 0935-1221.
93. Pekov, Igor V.; Zubkova, Natalia V.; Koshlyakova, Natalia N.; Belakovskiy, Dmitry I.; Agakhanov, Atali A.; Vigasina, Marina F.; Britvin, Sergey N.; Sidorov, Evgeny G.; Pushcharovsky, Dmitry Yu. (1 October 2020). "Rhabdoborite‑(V), rhabdoborite‑(Mo) and rhabdoborite‑(W): a new group of borate minerals with the general formula Mg₁₂M_1^1/3O₆[(BO₃)_6–x(PO₄)_xF_2–x] (M= V^5+, Mo^6+ or W^6+ and x < 1)". Physics and Chemistry of Minerals. 47 (10): 2–3. doi:10.1007/s00269-020-01105-7. ISSN 1432-2021. S2CID 222070921. Archived from the original on 14 October 2022. Retrieved 6 December 2020.
94. Campostrini, Italo; Demartin, Francesco; Scavini, Marco (2018). "Russoite, NH₄ClAs₂^3+O₃(H₂O)_0.5, a new phylloarsenite mineral from Solfatara Di Pozzuoli, Napoli, Italy". Mineralogical Magazine. 83 (1): 89. doi:10.1180/minmag.2017.081.097. hdl:2434/632951. ISSN 0026-461X. S2CID 134676998.
95. Shchipalkina, Nadezhda V.; Vereshchagin, Oleg S.; Pekov, Igor V.; Belakovskiy, Dmitry I.; Koshlyakova, Natalia N.; Shilovskikh, Vladimir V.; Pankin, Dmitriy V.; Britvin, Sergey N.; Sandalov, Fedor D.; Sidorov, Evgeny G. (3 July 2023). "Ryabchikovite, CuMg(Si2O6), a new pyroxene group mineral, and some genetic features of natural anhydrous copper silicates". American Mineralogist. 108 (7): 1399–1408. Bibcode:2023AmMin.108.1399S. doi:10.2138/am-2022-8620. S2CID 252170715. Archived from the original on 16 April 2024. Retrieved 9 March 2024.
96. Campostrini, Italo; Demartin, Francesco; Russo, Massimo (1 January 2019). "Sbacchiite, Ca₂AlF₇, a new fumarolic mineral from the Vesuvius volcano, Napoli, Italy". European Journal of Mineralogy. 31 (1): 153–158. Bibcode:2019EJMin..31..153C. doi:10.1127/ejm/2018/0030-2799. hdl:2434/633175. ISSN 0935-1221. S2CID 133815659.
97. Hughes, John M.; Finger, Larry W. (1 December 1983). "The crystal chemistry of shcherbinaite, naturally occurring V₂O₅". American Mineralogist. 68 (11–12): 1220. ISSN 0003-004X. Archived from the original on 30 October 2023. Retrieved 12 December 2020.
98. Birnie, R. W.; Hughes, J. M. (1 October 1979). "Stoiberite, Cu₅V₂O₁₀, a new copper vanadate from Izalco Volcano, El Salvador, Central America". American Mineralogist. 64 (9–10): 941. ISSN 0003-004X. Archived from the original on 18 August 2021. Retrieved 12 December 2020.
99. Demartin, F.; Castellano, C.; Campostrini, I. (2014). "Therasiaite, (NH₄)₃KNa₂Fe^2+Fe^3+(SO₄)₃Cl₅, a new sulfate chloride from La Fossa Crater, Vulcano, Aeolian islands, Italy". Mineralogical Magazine. 78 (1): 203–204. Bibcode:2014MinM...78..203D. doi:10.1180/minmag.2014.078.1.14. ISSN 0026-461X. S2CID 101488742. Archived from the original on 2021-05-03. Retrieved 2020-12-12.
100. Garavelli, Anna; Pinto, Daniela; Mitolo, Donatella; Kolitsch, Uwe (October 2021). "Thermessaite-(NH₄), (NH₄)₂AlF₃(SO₄), a new fumarole mineral from La Fossa crater at Vulcano, Aeolian Islands, Italy". Mineralogical Magazine. 85 (5): 665–672. Bibcode:2021MinM...85..665G. doi:10.1180/mgm.2021.69. ISSN 0026-461X. S2CID 239697198. Archived from the original on 2021-09-02. Retrieved 2021-12-08.
101. Balić-Žunić, Tonči; Garavelli, Anna; Mitolo, Donatella (1 July 2018). "Topsøeite, FeF₃(H₂O)₃, a new fumarolic mineral from the Hekla Volcano, Iceland". European Journal of Mineralogy. 30 (4): 841–848. Bibcode:2018EJMin..30..841B. doi:10.1127/ejm/2018/0030-2751. ISSN 0935-1221. S2CID 135331113.
102. Pekov, Igor V.; Britvin, Sergey N.; Krivovichev, Sergey V.; Yapaskurt, Vasiliy O.; Vigasina, Marina F.; Turchkova, Anna G.; Sidorov, Evgeny G. (1 April 2021). "Vasilseverginite, Cu₉O₄(AsO₄)₂(SO₄)₂, a new fumarolic mineral with a hybrid structure containing novel anion-centered tetrahedral structural units". American Mineralogist. 106 (4): 633–640. Bibcode:2021AmMin.106..633P. doi:10.2138/am-2020-7611. ISSN 0003-004X. S2CID 226659801. Archived from the original on 8 December 2021. Retrieved 8 December 2021.
103. Shablinskii, Andrey P.; Filatov, Stanislav K.; Vergasova, Lidyua P.; Avdontseva, Eugeniya Yu; Moskaleva, Svetlana V. (2018). "Wrightite, K₂Al₂O(AsO₄)₂, a new oxo-orthoarsenate from the Second scoria cone, Northern Breakthrough, Great Fissure eruption, Tolbachik volcano, Kamchatka peninsula, Russia". Mineralogical Magazine. 82 (6): 1243. Bibcode:2018MinM...82.1243S. doi:10.1180/minmag.2017.081.091. ISSN 0026-461X. S2CID 133798925.
104. Pekov, Igor V.; Siidra, Oleg I.; Yapaskurt, Vasiliy O.; Polekhovsky, Yury S.; Kartashov, Pavel M. (1 June 2018). "Ziminaite, Fe^3+VO₄, a new howardevansite-group mineral from the Bezymyannyi volcano, Kamchatka, Russia". Mineralogy and Petrology. 112 (3): 371. Bibcode:2018MinPe.112..371P. doi:10.1007/s00710-017-0550-y. ISSN 1438-1168. S2CID 133637568.
105. Pekov, Igor V.; Lykova, Inna; Koshlyakova, Natalia N.; Belakovskiy, Dmitry I.; Vigasina, Marina F.; Turchkova, Anna G.; Britvin, Sergey N.; Sidorov, Evgeny G.; Scheidl, Katharina S. (8 August 2020). "A new mineral species zincobradaczekite, NaCuCuZn₂(AsO₄)₃, and a new isomorphous series bradaczekite–zincobradaczekite in the alluaudite group". Physics and Chemistry of Minerals. 47 (8): 36. Bibcode:2020PCM....47...36P. doi:10.1007/s00269-020-01104-8. ISSN 1432-2021. S2CID 221049489. Archived from the original on 30 October 2023. Retrieved 6 December 2020.

Sources

• Borisov, Artem S.; Siidra, Oleg I.; Vlasenko, Natalia S.; Platonova, Natalia V.; Schuldt, Thies; Neuman, Mason; Strauss, Harald; Holzheid, Astrid (September 2024). "The Yadovitaya fumarole, Tolbachik volcano: A comprehensive mineralogical and geochemical study and driving factors for mineral diversity". Geochemistry. 84 (3): 126179. Bibcode:2024ChEG...84l6179B. doi:10.1016/j.chemer.2024.126179.
• Britvin, S. N.; Pekov, I. V.; Yapaskurt, V. O.; Koshlyakova, N. N.; Göttlicher, J.; Krivovichev, S. V.; Turchkova, A. G.; Sidorov, E. G. (14 April 2020). "Polyoxometalate chemistry at volcanoes: discovery of a novel class of polyoxocuprate nanoclusters in fumarolic minerals". Scientific Reports. 10 (1): 6345. Bibcode:2020NatSR..10.6345B. doi:10.1038/s41598-020-63109-1. ISSN 2045-2322. PMC 7156706. PMID 32286401.
• Cámara, Fernando; Gagne, Olivier C.; Uvarova, Yulia (1 February 2015). "New Mineral Names" (PDF). American Mineralogist. 100 (2–3): 658–663. Bibcode:2015AmMin.100..658C. doi:10.2138/am-2015-NMN10024. ISSN 0003-004X. S2CID 199470275.
• Ganino, Clément; Libourel, Guy; Bernard, Alain (1 May 2019). "Fumarolic incrustations at Kudryavy volcano (Kamchatka) as a guideline for high-temperature (>850 °C) extinct hydrothermal systems". Journal of Volcanology and Geothermal Research. 376: 75–85. Bibcode:2019JVGR..376...75G. doi:10.1016/j.jvolgeores.2019.03.020. ISSN 0377-0273.
• Guy, Bernard; Thiéry, Vincent; Garcia, Daniel; Bascou, Jérôme; Broekmans, Maarten A.T.M. (1 December 2020). "Columnar structures in pyrometamorphic rocks associated with coal-bearing spoil-heaps burned by self-ignition, La Ricamarie, Loire, France". Mineralogy and Petrology. 114 (6): 465–487. Bibcode:2020MinPe.114..465G. doi:10.1007/s00710-020-00719-7. ISSN 1438-1168. S2CID 221146105. Archived from the original on 21 June 2022. Retrieved 5 December 2020.
• Keith, Terry E. C. (1 April 1991). "Fossil and active fumaroles in the 1912 eruptive deposits, Valley of ten thousand smokes, Alaska". Journal of Volcanology and Geothermal Research. 45 (3): 227–254. Bibcode:1991JVGR...45..227K. doi:10.1016/0377-0273(91)90061-4. ISSN 0377-0273. Archived from the original on 28 June 2024. Retrieved 13 December 2020.
• Kodosky, Lawrence G.; Keith, Terry E. C. (1 March 1993). "Factors controlling the geochemical evolution of fumarolic encrustations, Valley of Ten Thousand Smokes, Alaska". Journal of Volcanology and Geothermal Research. 55 (3): 185–200. Bibcode:1993JVGR...55..185K. doi:10.1016/0377-0273(93)90036-Q. ISSN 0377-0273. Archived from the original on 30 October 2023. Retrieved 13 December 2020.
• Pekov, Igor V.; Koshlyakova, Natalia N.; Zubkova, Natalia V.; Lykova, Inna S.; Britvin, Sergey N.; Yapaskurt, Vasiliy O.; Agakhanov, Atali A.; Shchipalkina, Nadezhda V.; Turchkova, Anna G.; Sidorov, Evgeny G. (1 March 2018). "Fumarolic arsenates − a special type of arsenic mineralization". European Journal of Mineralogy. 30 (2): 305–322. Bibcode:2018EJMin..30..305P. doi:10.1127/ejm/2018/0030-2718. ISSN 0935-1221. S2CID 134438306. Archived from the original on 28 June 2024. Retrieved 6 December 2020.
• Pinto, D.; Garavelli, A.; Mitolo, D. (1 August 2014). "Balićžunićite, Bi₂O(SO₄)₂, a new fumarole mineral from La Fossa crater, Vulcano, Aeolian Islands, Italy". Mineralogical Magazine. 78 (4): 1043–1055. Bibcode:2014MinM...78.1043P. doi:10.1180/minmag.2014.078.4.15. ISSN 0026-461X. S2CID 131223258. Archived from the original on 28 February 2021. Retrieved 5 December 2020 – via ResearchGate.
• Renggli, C. J.; Klemme, S. (1 August 2020). "Experimental constraints on metal transport in fumarolic gases". Journal of Volcanology and Geothermal Research. 400: 106929. Bibcode:2020JVGR..40006929R. doi:10.1016/j.jvolgeores.2020.106929. ISSN 0377-0273. S2CID 219452854. Archived from the original on 28 June 2024. Retrieved 5 December 2020.
• Shchipalkina, Nadezhda V.; Pekov, Igor V.; Koshlyakova, Natalia N.; Britvin, Sergey N.; Zubkova, Natalia V.; Varlamov, Dmitry A.; Sidorov, Eugeny G. (29 January 2020). "Unusual silicate mineralization in fumarolic sublimates of the Tolbachik volcano, Kamchatka, Russia – Part 1: Neso-, cyclo-, ino- and phyllosilicates". European Journal of Mineralogy. 32 (1): 101–119. Bibcode:2020EJMin..32..101S. doi:10.5194/ejm-32-101-2020. ISSN 0935-1221. Archived from the original on 28 November 2020. Retrieved 6 December 2020.
• Stoiber, Richard E.; Rose, William I. (1 April 1974). "Fumarole incrustations at active central american volcanoes". Geochimica et Cosmochimica Acta. 38 (4): 495–516. Bibcode:1974GeCoA..38..495S. doi:10.1016/0016-7037(74)90037-4. ISSN 0016-7037. Archived from the original on 28 June 2024. Retrieved 13 December 2020.
• Stracher, Glenn B.; Prakash, Anupma; Schroeder, Paul; McCormack, John; Zhang, Xiangmin; Dijk, Paul Van; Blake, Donald (1 November 2005). "New mineral occurrences and mineralization processes: Wuda coal-fire gas vents of Inner Mongolia". American Mineralogist. 90 (11–12): 1729–1739. Bibcode:2005AmMin..90.1729S. doi:10.2138/am.2005.1671. ISSN 0003-004X. S2CID 129398563. Archived from the original on 2 June 2018. Retrieved 12 December 2020.
• Vergasova, L. P.; Filatov, S. K.; Dunin-Barkovskaya, V. V. (1 April 2007). "Posteruptive activity on the First Cone of the Great Tolbachik Fissure Eruption and recent volcanogenic generation of bauxites". Journal of Volcanology and Seismology. 1 (2): 119–139. Bibcode:2007JVolS...1..119V. doi:10.1134/S0742046307020030. ISSN 1819-7108. S2CID 128613101. Archived from the original on 7 June 2018. Retrieved 5 December 2020.
• Yudovskaya, Marina A.; Distler, Vadim V.; Chaplygin, Ilya V.; Mokhov, Andrew V.; Trubkin, Nikolai V.; Gorbacheva, Sonya A. (March 2006). "Gaseous transport and deposition of gold in magmatic fluid: evidence from the active Kudryavy volcano, Kurile Islands". Mineralium Deposita. 40 (8): 828–848. Bibcode:2006MinDe..40..828Y. doi:10.1007/s00126-005-0034-6. S2CID 128416311.