Two-colour symmetry (examples, history and dimensional counts)
Dichromatic symmetry,[1] also referred to as antisymmetry,[2][3] black-and-white symmetry,[4] magnetic symmetry,[5] counterchange symmetry[6] or dichroic symmetry,[7] is a symmetry operation which reverses an object to its opposite.[8] A more precise definition is "operations of antisymmetry transform objects possessing two possible values of a given property from one value to the other."[9] Dichromatic symmetry refers specifically to two-coloured symmetry; this can be extended to three or more colours in which case it is termed polychromatic symmetry.[10] A general term for dichromatic and polychromatic symmetry is simply colour symmetry. Dichromatic symmetry is used to describe magnetic crystals and in other areas of physics,[11] such as time reversal,[12] which require two-valued symmetry operations.
Examples
A simple example is to take a white object, such as a triangle, and apply a colour change resulting in a black triangle. Applying the colour change once more yields the original white triangle.
The colour change, here termed an anti-identity operation (1'), yields the identity operation (1) if performed twice.
Another example is to construct an anti-mirror reflection (m') from a mirror reflection (m) and an anti-identity operation (1') executed in either order.
The m' operation can then be used to construct the antisymmetry point group 3m' of a dichromatic triangle.
There are no mirror reflection (m) operations for the dichromatic triangle, as there would be if all the smaller component triangles were coloured white. However, by introducing the anti-mirror reflection (m') operation the full dihedral D3 symmetry is restored. The six operations making up the dichromatic D3 (3m') point group are:
identity (e)
rotation by 2π/3 (r)
rotation by 4π/3 (r2)
anti-mirror reflection (m')
combination of m' with r (m'r)
combination of m' with r2 (m'r2).
Note that the vertex numbers do not form part of the triangle being operated on - they are shown to keep track of where the vertices end up after each operation.
History
In 1930 Heinrich Heesch was the first person to formally postulate an antisymmetry operation in the context of examining the 3D space groups in 4D.[13] Heesch's work was influenced by Weber's 1929 paper on black-and-white colouring of 2D bands.[14]
In 1935-1936 H.J. Woods published a series of four papers with the title The geometrical basis of pattern design. The last of these[15] was devoted to counterchange symmetry and in which was derived for the first time the 46 dichromatic 2D point groups.
The work of Heesch and Woods were not influential at the time, and the subject of dichromatic symmetry did not start to become important until the publication of A.V. Shubnikov's book Symmetry and antisymmetry of finite figures in 1951. Thereafter the subject developed rapidly, initially in Russia but subsequently in many other countries, because of its importance in magnetic structures and other physical fields.
1951 Landau and Lifshitz reinterpret black and white colours to correspond to time reversal symmetry[16]
1953 Zamorzaev derives the 1651 3D antisymmetric space groups for the first time[17][18]
1956 Tavger and Zaitsev use the concept of vector reversal of magnetic moments to derive point groups for magnetic crystals[19]
1957 Belov and his colleagues independently derive the 2D and 3D antisymmetric groups[20]
1957 Zamorzaev and Sokolov begin the generalization of antisymmetry by introducing the concept of more than one kind of two-valued antisymmetry operation[11][21][22][23]
The table below gives the number of ordinary and dichromatic groups by dimension. The Bohm[37] symbol is used to denote the number of groups where = overall dimension, = lattice dimension and = number of antisymmetry operation types. for dichromatic groups with a single antisymmetry operation .
^ abcShubnikov, A.V. (1951). Symmetry and antisymmetry of finite figures, Izv. Akad. Nauk SSSR, Moscow
^ abShubnikov, A.V., Belov, N.V. et. al. (1964). Colored symmetry, ed. W.T. Holser, Pergamon, New York
^Gévay, G. (2000). Black-and-white symmetry, magnetic symmetry, self-duality and antiprismatic symmetry: the common mathematical background, Forma, 15, 57–60
^Tavger, B.A. (1958). The symmetry of ferromagnetics and antiferromagnetics, Sov. Phys. Cryst., 3, 341-343
^Woods, H.J. (1935). The geometric basis of pattern design part I: point and line symmetry in simple figures and borders, Journal of the Textile Institute, Transactions, 26, T197-T210
^Makovicky, E. (2016). Symmetry through the eyes of old masters, de Gruyter, Berlin, ISBN9783110417050
^Atoji, A. (1965). Graphical representations of magnetic space groups, American Journal of Physics, 33(3), 212–219, doi:10.1119/1.1971375
^ abPadmanabhan, H., Munro, J.M., Dabo, I and Gopalan, V. (2020). Antisymmetry: fundamentals and applications, Annual Review of Materials Research, 50, 255-281, doi:10.1146/annurev-matsci-100219-101404
^Shubnikov, A.V. (1960). Time reversal as an operation of antisymmetry, Sov. Phys. Cryst., 5, 309-314
^ abHeesch, H. (1930). Über die vierdimensionalen Gruppen des dreidimensionalen Raumes, Z. Krist., 73, 325-345, doi:10.1524/zkri.1930.73.1.325
^Woods, H.J. (1936). The geometric basis of pattern design part IV: counterchange symmetry in plane patterns, Journal of the Textile Institute, Transactions, 27, T305-320
^Landau, L.D. and Lifshitz E.M. (1951). Course of theoretical physics, vol. 5. Statistical physics, 1st edition, Nauka, Moscow
^ abZamorzaev, A.M. (1953). Generalization of the space groups, Dissertation, Leningrad University
^Tavger, B.A. and Zaitsev, V.M. (1956). Magnetic symmetry of crystals, Soviet Physics JETP, 3(3), 430-436
^ abBelov, N.V., Neronova, N.N. and Smirnova, T.S. (1957). Shubnikov groups, Sov. Phys. Cryst., 2, 311-322
^Zamorzaev, A.M. and Sokolov, E.I. (1957). Symmetry and various kinds of antisymmetry of finite bodies, Sov. Phys. Cryst., 2, 5-9
^Zamorzaev, A.M. and Palistrant, A.F. (1980). Antisymmetry, its generalizations and geometrical applications, Z. Krist., 151, 231-248, doi:10.1524/zkri.1980.151.3-4.231
^Koptsik, V.A. (1968). A general sketch of the development of the theory of symmetry and its applications in physical crystallography over the last 50 years, Sov. Phys. Cryst., 12(5), 667-683
^Brückler, F.M. and Stilinović, V. (2024) From friezes to quasicrystals: a history of symmetry groups, 1-42, doi:10.1007/978-3-030-19071-2_132-2, in Sriraman, B. (ed.) Handbook of the history and philosophy of mathematical practice, Springer, pp 3200, ISBN978-3-030-19071-2
^Opechowski, W. and Guccione, R. (1965). Magnetic symmetry in Magnetism, vol. IIA ed. Rado, G.T. and Suhl, H., Academic Press, New York, pp 105-165
^Koptsik, V.A. (1966). Shubnikov groups: Handbook on the symmetry and physical properties of crystal structures, Moscow University, Moscow
^ abcShubnikov, A.V. and Koptsik, V.A. (1974). Symmetry in science and art, Plenum Press, New York, ISBN9780306307591 (original in Russian published by Nauka, Moscow, 1972.)
^Conway, J.H., Burgeil, H. and Goodman-Strauss, C. (2008). The symmetries of things, A.K. Peters, Wellesley, MA, ISBN9781568812205
^Bohm, J. and Dornberger-Schiff, K. (1966). The nomenclature of crystallographic symmetry groups, Acta Crystallogr., 21, 1000-1007, doi:10.1107/S0365110X66004389
^Fedorov, E.S. (1891). "Симметрія на плоскости" [Simmetriya na ploskosti, Symmetry in the plane]. Записки Императорского С.-Петербургского Минералогического Общества (Zapiski Imperatorskova Sankt-Petersburgskova Mineralogicheskova Obshchestva, Proceedings of the Imperial St. Petersburg Mineralogical Society). 2nd series (in Russian). 28: 345–390.
^Pólya, G. (1924). Über die Analogie der Kristallsymmetrie in der Ebene (On the analog of crystal symmetry in the plane), Z. Krist., 60, 278–282, doi:10.1524/zkri.1924.60.1.278
^Alexander, E. and Herrman, K. (1929). Die 80 zweidimensionalen Raumgruppen, Z. Krist. 70, 328-345, doi:10.1524/zkri.1929.70.1.328
^Neronova, N.N. and Belov, N.V. (1961). A single scheme for the classical and black-and-white crystallographic symmetry groups, Sov. Phys. Cryst., 6, 3-12
^Burckhardt, J.J. (1967). Zur Geschichte der Entdeckung der 230 Raumgruppen [On the history of the discovery of the 230 space groups], Archive for History of Exact Sciences, 4(3), 235-246, doi:10.1007/BF00412962
^ abBrown, H., Bulow, R., Neubuser, J. et. al. (1978). Crystallographic groups of four-dimensional space, Wiley, New York, ISBN9780471030959
^Palistrant, A.F. and Zamorzaev, A.M. (1992). Symmetry space groups: on the 100th anniversary of their discovery, ed. Vainshtein, B.K., Nauka, Moscow (in Russian)
^Zamorzaev, A.M., Karpova, Yu.S., Lungu, A.P. and Palistrant, A.F. (1986). P-symmetry and its further development, Shtiintsa, Chisinau (in Russian)