丙酸铀酰 是一种六价铀的羧酸盐,化学式为UO2 (C2 H5 COO)2 。它可由三氧化铀 和丙酸 反应得到。[ 1] 它的热分解产物为八氧化三铀 。[ 1] 它的二水合物和尿素 反应,可以得到UO2 (C2 H5 COO)2 ·2CO(NH2 )2 ·H2 O。[ 2] 它和丙酸镁 反应,可以得到Mg[UO2 (C2 H5 COO)3 ]2 ·6H2 O。[ 3]
参考文献
^ 1.0 1.1 R. M. Rojas, J. Bermudez, E. Criado. Thermal decomposition of uranyl propionate dihydrate . Journal of Thermal Analysis. 1971-09, 3 (3): 277–280 [2022-08-16 ] . ISSN 0022-5215 . doi:10.1007/BF01912111 (英语) .
^ V. N. Serezhkin, M. S. Grigor’ev, A. R. Abdul’myanov, L. B. Serezhkina. Structure and some properties of UO2(C2H5COO)2 · nQ · mH2O (Q is carbamide or ethylenecarbamide) . Russian Journal of Inorganic Chemistry. 2016-01, 61 (1): 24–32 [2022-08-16 ] . ISSN 0036-0236 . doi:10.1134/S0036023616010228 (英语) .
^ Viktor N. Serezhkin, Mikhail S. Grigoriev, Aleksey R. Abdulmyanov, Aleksandr M. Fedoseev, Anton V. Savchenkov, Larisa B. Serezhkina. Synthesis and X-ray Crystallography of [Mg(H 2 O) 6 ][AnO 2 (C 2 H 5 COO) 3 ] 2 (An = U, Np, or Pu) . Inorganic Chemistry. 2016-08-01, 55 (15): 7688–7693 [2022-08-16 ] . ISSN 0020-1669 . doi:10.1021/acs.inorgchem.6b01154 . (原始内容存档 于2022-03-05) (英语) .
拓展阅读
Alikhanova, Z. M.; Zolin, V. F.; Fisher, P. S.; Ellert, G. V. Luminescence spectra and structure of uranyl propionates(俄文) . Zhurnal Neorganicheskoi Khimii , 1970. 15 (11): 3119-3123.