Thulium monoselenide

Thulium monoselenide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.031.711 Edit this at Wikidata
EC Number
  • 234-896-1
  • InChI=1S/Se.Tm
    Key: GFKHZESYKBWHEV-UHFFFAOYSA-N
  • [Se]=[Tm]
Properties
TmSe
Molar mass 247.89
Density 9.1 g/cm3
Melting point 2,060 °C (3,740 °F; 2,330 K)
Related compounds
Other anions
 TmS
TmTe
Other cations
 ErSe
YbSe
Related compounds
 Tm2Se3
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Thulium monoselenide is a mixed valence[1] compound of selenium and thulium with the chemical formula TmSe.

Preparation

Thulium monoselenide can be prepared by directly reacting thulium and selenium:[2]

Tm + Se → TmSe

Properties

Thulium monoselenide forms reddish-brown cubic crystals,[2] space group Fm3m, unit cell parameters a = 0.5640 nm, Z = 4, and a structure similar to that of sodium chloride.[3][4][2]

The compound melts congruently at 2060 °C, and at 1100 °C and 1730 °C, phase transitions occur in the compound. The Néel temperature of thulium monoselenide is 1.85–2.8 K.[2]

References

  1. ^ Kaindl, G.; Brewer, W. D.; Kalkowski, G.; Holtzberg, F. (1983-11-28). "$M$-Edge X-Ray Absorption Spectroscopy: A New Tool for Dilute Mixed-Valent Materials". Physical Review Letters. 51 (22): 2056–2059. doi:10.1103/PhysRevLett.51.2056.
  2. ^ a b c d Bucher, E.; Andres, K.; di Salvo, F. J.; Maita, J. P.; Gossard, A. C.; Cooper, A. S.; Hull, G. W. (1975-01-01). "Magnetic and some thermal properties of chalcogenides of Pr and Tm and a few other rare earths". Physical Review B. 11 (1): 500–513. Bibcode:1975PhRvB..11..500B. doi:10.1103/PhysRevB.11.500.
  3. ^ Predel, B. (1998), "Se-Tm (Selenium-Thulium)", Pu-Re – Zn-Zr, Landolt-Börnstein - Group IV Physical Chemistry, vol. 5 J, Berlin/Heidelberg: Springer-Verlag, pp. 1–2, doi:10.1007/10551312_2721, ISBN 3-540-61742-6, retrieved 2024-01-22
  4. ^ Diagrammy sostojanija dvojnych metalličeskich sistem: spravočnik v trech tomach. 3,2. Moskva: Mašinostroenie. 2001. ISBN 978-5-217-02932-7.