4-氯异丙苯

4-氯异丙苯
识别
CAS号 2621-46-7  checkY
SMILES
 
  • ClC1=CC=C(C=C1)C(C)C
性质
化学式 C9H11Cl
摩尔质量 154.64 g·mol−1
熔点 −12.3 °C[1]
沸点 198.3 °C[1]
若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

4-氯异丙苯是一种有机氯化合物，化学式为C9H11Cl。它可由异丙苯和氯气在乙酸中，或和次氯酸叔丁酯在沸石存在下于乙腈中反应制得，该反应会产生少量的2-氯异丙苯。[2]在氯化亚铁催化下，它可以被过氧化氢氧化为4'-氯苯乙酮。[3]

参考文献

  1. ^ 1.0 1.1 "PhysProp" data were obtained from Syracuse Research Corporation of Syracuse, New York (US). Retrieved from SciFinder. [2024-07-02].
  2. ^ Smith, Keith; Butters, Michael; Nay, Barry. Highly para-Selective Mono-Chlorination of Aromatic Compounds Under Mild Conditions by t-Butyl Hypochlorite in the Presence of Zeolites. Synthesis, 1985 (12), 1157–1158. doi:10.1055/s-1985-31462
  3. ^ Ning Xu, Lulu Zhou, Linlin Zhao, Mengying Guo, Linlin Yang, Wei Han. Iron-Catalyzed Oxidative C−C Bond Cleavage of Unstrained Tertiary Alkyl Aromatics to Arylketones. Advanced Synthesis & Catalysis. 2023. 365 (15). doi:10.1002/adsc.202300410.