2,1-苯并异𫫇唑是一种有机化合物,化学式为C7H5NO。它是三种结构异构体中稳定性最差的物种。[2]它可由2-硝基苯甲醛氢化还原[3]或用氯化亚锡还原[4]制得。
它和丙二腈在乙醇中反应,可以得到2-氨基喹啉-3-甲基-N-氧化物。[5]
参考文献
- ^ 1.0 1.1 1.2 1.3 来源:Sigma-Aldrich Co., Anthranil (2017-03-02查阅).
- ^ Domene, Carmen; Jenneskens, Leonardus W.; Fowler, Patrick W. Aromaticity of anthranil and its isomers, 1,2-benzisoxazole and benzoxazole. Tetrahedron Letters. 2005, 46 (23): 4077–4080. ISSN 0040-4039. doi:10.1016/j.tetlet.2005.04.014. hdl:1874/14837 .
- ^ Marti, L.; et al. Chemoselective Reductive Heterocyclization by Controlling the Binomial Architecture of Metal Particles and Acid-Base Properties of the Support. ACS Catal. 2017, 7, 12, 8255–8262. doi:10.1021/acscatal.7b01841.
- ^ Ping-Gui Li; et al. Copper-catalyzed coupling of anthranils and α-keto acids: direct synthesis of α-ketoamides. Org. Biomol. Chem., 2019,17, 5902-5907. doi:10.1039/C9OB00822E.
- ^ Edward C. Taylor; Juan Bartulin. Ring expansion of anthranil to quinoline 1-oxides. Tetrahedron Letters, 1967. 25 (8): 2337-2339. doi:10.1016/S0040-4039(00)71601-7.