1-十四烯

1-十四烯
英文名 1-Tetradecene
识别
CAS号 1120-36-1  checkY
PubChem 14260
ChemSpider 13622
SMILES
 
  • CCCCCCCCCCCCC=C
InChI
 
  • 1S/C14H28/c1-3-5-7-9-11-13-14-12-10-8-6-4-2/h3H,1,4-14H2,2H3
InChIKey HFDVRLIODXPAHB-UHFFFAOYSA-N
ChEBI 77505
性质
化学式 C14H28
摩尔质量 196.37 g·mol−1
若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

1-十四烯（英語：1-Tetradecene）是一种有机化合物，化学式C14H28，存在于焦曲霉（Aspergillus ustus）[1]、香莢蘭（Vanilla planifolia）[2]等物种中。它在光照和Pd/BiOBr/BiVO4催化下，可以被乙醇还原为正十四烷。[3]

参考资料

  1. ^ Oleinikova, G. K.; Slinkina, N. N.; Afiyatullov, Sh. Sh. Nonpolar compounds and free fatty acids from marine fungi Aspergillus ustus. Chemistry of Natural Compounds. 2011-11, 47 (5): 805–806. doi:10.1007/S10600-011-0066-3. 
  2. ^ Ramaroson-Raonizafinimanana, Béatrice; Gaydou, Émile M.; Bombarda, Isabelle. Hydrocarbons from Three Vanilla Bean Species: V. fragrans , V. madagascariensis , and V. tahitensis. Journal of Agricultural and Food Chemistry. 1997-07-01, 45 (7): 2542–2545. doi:10.1021/JF960927B. 
  3. ^ Miller, Edward B.; Knecht, Marc R.; Bachas, Leonidas G. Photocatalytic Approaches for Sustainable Olefin Transfer Hydrogenation and Semihydrogenation of Alkynes Using Natural Sunlight. ACS Applied Energy Materials (2022), 5(9), 11052-11057. doi:10.1021/acsaem.2c01643.