| 金边酮
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IUPAC名
8-Methyl-13-methylene-14β-(3-oxobutyl)podocarpan-17-al
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系统名
(4aR,4bS,8R,8aS,10aS)-1,1,8a-Trimethyl-7-methylidene-8-(3-oxobutyl)dodecahydrophenanthrene-4a(2H)-carbaldehyde
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| 识别
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| CAS号
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80902-35-8  Y
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| PubChem
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21601966
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| ChemSpider
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10232770
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| SMILES
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- CC(=O)CC[C@@H]3C(=C)CC[C@H]2[C@@]3(C)CC[C@@H]1[C@]2(C=O)CCCC1(C)C
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| InChI
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- 1/C23H36O2/c1-16-7-10-20-22(5,18(16)9-8-17(2)25)14-11-19-21(3,4)12-6-13-23(19,20)15-24/h15,18-20H,1,6-14H2,2-5H3/t18-,19+,20+,22+,23-/m1/s1
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| InChIKey
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KSJHEGGDTGLBND-UZCBEENBBA
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| 性质
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| 化学式
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C23H36O2
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| 摩尔质量
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344.53 g·mol−1
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| 外观
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白色晶体[1]
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| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。
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金边酮是一种23碳的类萜有机化合物，化学式为C23H36O2，它来自于金边卡海牛中，被认为是该物种散发出的愉悦果味的物质来源。[2]
它的单晶结构通过2,4-二硝基苯腙衍生物推定得出。[2]
参考文献
- ^ Julia Kubanek; Edmund I. Graziani; Raymond J. Andersen. Investigations of Terpenoid Biosynthesis by the Dorid Nudibranch Cadlina luteomarginata. J. Org. Chem. 1997, 62, 21, 7239–7246. doi:10.1021/jo970695v.
- ^ 2.0 2.1 Hellou, Jocelyne; Andersen, Raymond J.; Rafii, Shahin; Arnold, Edward; Clardy, Jon. Luteone, a twenty three carbon terpenoid from the dorid nudi branch Cadlina luteomarginata. Tetrahedron Letters. 1981, 22 (42): 4173. doi:10.1016/S0040-4039(01)82096-7.
