环癸烯

环癸烯
IUPAC名
(E)-Cyclodecene, (Z)-Cyclodecene
别名 cis-Cyclodecene, trans-Cyclodecene
识别
CAS号 3618-12-0  checkY
2198-20-1（E）  checkY
935-31-9（Z）  checkY
ChemSpider 4517575
SMILES
 
  • C\1=C\CCCCCCCC/1
性质
化学式 C10H18
摩尔质量 138.25 g·mol−1
密度 0.887 g/cm−3（0 °C）[1]
0.8681 g/cm−3（E, 20 °C）[2]
0.8743 g/cm−3（Z, 20 °C）[2]
沸点 143—144 °C（416—417 K）[1]
198—199 °C（471—472 K）[3]
194—195 °C（467—468 K）[4]
若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

环癸烯（化学式：C10H18）是十个碳的环烯烃。

性质

环癸烯具有烯烃的通性，如可以发生臭氧化反应[5]、和卤素的加成反应[6][7]、环氧化反应[8]等。

参见

参考文献

  1. ^ 1.0 1.1 Willstatter, Richard; Veraguth, Hans. Cyclooctane Series. II. Communication. Berichte der Deutschen Chemischen Gesellschaft, 1907. 40. 959-970. ISSN: 0365-9496.
  2. ^ 2.0 2.1 Schenker, Prelog, K.; Gunthard, H. H. Carbon rings. LX. The ten-membered ring. V. Helvetica Chimica Acta, 1952. 35: 1598-1615. ISSN: 0018-019X.
  3. ^ Richard B. Turner, W. R. Meador. Heats of Hydrogenation. IV. Hydrogenation of Some cis- and trans-Cycloölefins 1. Journal of the American Chemical Society. 1957-08, 79 (15): 4133–4136 [2020-05-02]. ISSN 0002-7863. doi:10.1021/ja01572a042 （英语）. 
  4. ^ A. T. Blomquist, Robert E. Burge, Arthur C. Sucsy. Many-Membered Carbon Rings. V. Cyclodecyne, cis- and trans-Cyclodecene and Related Compounds 1. Journal of the American Chemical Society. 1952-07, 74 (14): 3636–3642 [2020-05-02]. ISSN 0002-7863. doi:10.1021/ja01134a051. （原始内容存档于2019-12-30） （英语）. 
  5. ^ Karl Griesbaum, Willi Volpp, Reinhard Greinert, Hans Joachim Greunig, Juergen Schmid, Henning Henke. Ozonolysis of tetrasubstituted ethylenes, cycloolefins, and conjugated dienes on polyethylene. The Journal of Organic Chemistry. 1989-01, 54 (2): 383–389 [2020-05-02]. ISSN 0022-3263. doi:10.1021/jo00263a023 （英语）. 
  6. ^ Tarchini, Claudio; Tran Dinh An; Jan, Gerald; Schlosser, Manfred. Base-promoted elimination reactions. Part 8. Hydroxide-promoted hydrogen halide cleavage of vic-dihalides under heterogeneous conditions: reaction outcome due to surprising solvent and metal effects. Helvetica Chimica Acta, 1979. 62 (2): 635-640. ISSN: 0018-019X.
  7. ^ Kaushik, M. P.; Polshettiwar, Vivek. N-Octylquinolinium tribromide: a task specific quinoline based ionic liquid as a new brominating agent. Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 2006. 45B (11): 2542-2545. ISSN: 0376-4699.
  8. ^ Tatiana R. Amarante, Patrícia Neves, Filipe A. Almeida Paz, Martyn Pillinger, Anabela A. Valente, Isabel S. Gonçalves. A dinuclear oxomolybdenum(VI) complex, [Mo2O6(4,4′-di-tert-butyl-2,2′-bipyridine)2], displaying the {MoO2(μ-O)2MoO2}0 core, and its use as a catalyst in olefin epoxidation. Inorganic Chemistry Communications. 2012-06, 20: 147–152 [2020-05-02]. doi:10.1016/j.inoche.2012.02.038 （英语）.