O2F2 可以和红磷反应, 即使在 -196 °C 仍会爆炸。三氟氯甲烷可以用来减缓爆炸力度。[9]
二氟化三氧(O3F2)
O3F2 是一种血红色液体。它在 90 K 就是液体,与熔点 109 K 的O2F2不同,可用来分辨两者。[11][3]
和其他氧的氟化物一样, O3F2 极易分解,于 115 K 迅速分解,反应如下:
参考资料
^Solomon, I. J. et al. Additional Studies Concerning the Existence of O3F2. Journal of the American Chemical Society. 1968, 90 (20): 5408–5411. doi:10.1021/ja01022a014.
^Misochko, Eugenii Ya, Alexander V. Akimov, Charles A. Wight. Infrared spectroscopic observation of the stabilized Intermediate complex FO3 formed by reaction of mobile Fluorine atoms with ozone molecules Trapped in an Argon Matrix. The Journal of Physical Chemistry A. 1999, 103 (40): 7972–7977. Bibcode:1999JPCA..103.7972M. doi:10.1021/jp9921194.
^Streng, A. G., A. V. Grosse. Two New Fluorides of Oxygen, O5F2 and O6F2. Journal of the American Chemical Society. 1966, 88: 169–170. doi:10.1021/ja00953a035.
^Jäger, Susanne et al. Fluorine and Oxygen. Fluorine. Berlin, Heidelberg: Springer. 1986: 1–161.
^Lawless, Edward W., Ivan C. Smith. Inorganic high-energy oxidizers: synthesis, structure, and properties. M. Dekker. 1968.
^Marx, Rupert, Konrad Seppelt. Structure investigations on oxygen fluorides. Dalton Transactions. 2015, 44 (45): 19659–19662. PMID 26351980. doi:10.1039/c5dt02247a.
^ 9.09.1Solomon, Irvine J. Research on Chemistry of and . No. IITRI-C227-6. IIT RESEARCH INST CHICAGO IL, 1964.
^Goetschel, Charles T. et al. Low-Temperature Radiation Chemistry. I. Preparation of Oxygen Fluorides and Dioxygenyl Tetrafluoroborate. Journal of the American Chemical Society. 1969, 91 (17): 4702–4707. doi:10.1021/ja01045a020.
^De Marco, Ronald A., and Jean'ne M. Shreeve . "Fluorinated Peroxides." Advances in Inorganic Chemistry and Radiochemistry. Vol. 16. Academic Press, 1974. 109-176.