乙酰丙酮镥

乙酰丙酮镥
识别
CAS号 17966-84-6  checkY
性质
化学式 C15H21LuO6
摩尔质量 472.29 g·mol−1
若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

乙酰丙酮镥是一种配位化合物，化学式为Lu(C5H7O2)3，或简写为Lu(acac)3，它和乙酰丙酮镱同构。[1]它可由三烷氧基镧和乙酰丙酮反应制得。[2]

它的二水合物和邻菲啰啉（phen）或2,2'-联吡啶（dipy）在乙醇溶液中回流，可以得到混合配体配合物Lu(acac)3(phen)和Lu(caca)3(dipy)。[3]

参考文献

  1. ^ Trembovetskii, G. V.; Martynenko, L. I.; Murav'eva, I. A.; Spitsyn, V. I. Synthesis and study of volatile rare earth acetylacetonates（俄文）. Doklady Akademii Nauk SSSR, 1984. 277 (6): 1411-1414. ISSN 0002-3264.
  2. ^ Gavrilenko, V. V.; Chekulaeva, L. A.; Savitskaya, I. A.; Garbuzova, I. A. Synthesis of yttrium, lanthanum, neodymium, praseodymium and lutetium alkoxides and acetylacetonates（俄文）. Izvestiya Akademi Nauk, Seriya Khimicheskaya, 1992. 11: 2490-2493. ISSN 1026-3500.
  3. ^ Andrey Yu. Rogachev, Andrey V. Mironov, Sergey I. Troyanov, Natalia P. Kuzmina, Alexander V. Nemukhin. Synthesis, crystal structures and theoretical study of mixed ligand complexes of lanthanides acetylacetonates with o-phenanthroline and 2,2′-dipyridyl: The unexpected inverted electrostatic trend in stability. Journal of Molecular Structure. 2006-05, 789 (1-3): 187–194 [2021-09-20]. doi:10.1016/j.molstruc.2005.12.026. （原始内容存档于2020-02-25） （英语）.