The sixth Desert Sessions EP was recorded in sessions between March 11 and 14, 1999 at Rancho De La Luna in Joshua Tree, California, a studio founded by Fred Drake and Dave Catching.[1][2][3][4] The tracks on Volume 6 were engineered by Steve Feldman, with Tony Mason assisting, and feature a total of eleven credited musicians: Josh Homme (guitars, vocals, bass, drums and percussion), Brant Bjork, Catching (both guitar), Gene Trautmann (drums and percussion), Fugitive Pope (vocals, guitar and electronics), Digital D (vocals and guitar), Chizm (vocals and bass), Drake (percussion), Van Conner, Hosh Ross Sonjoni (boh bass), Barrett Martin and Adam Maples (both drums).[1][2][3][4] Homme mixed the album, and it was mastered by Dave Schultz at DigiPrep in Hollywood, Los Angeles, California.[1][2][3][4]
Volume 6 was initially released alone on vinyl by Man's Ruin Records on August 16, 1999. It later received a re-release with its predecessor, Volume 5: Poetry for the Masses (SeaShedShitheadByTheSheSore), on CD on September 14, 1999 as Volumes 5 & 6.[5]