User talk:JohnSRoberts99/Archive 1
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THTTo address the question you pose in a recent edit summary: Wikipedia aims preferrentially cite encyclopedias, books, and reviews, not patents and not journal articles. The guideline is WP:SECONDARY. It is impossible to cover primary literature such as patents (which are usually quite useless sources of information except to specialists who can parse the legal jargon. People tend to cite journal articles because they do not have access to or are not aware of secondary sources.--Smokefoot (talk) 12:09, 20 May 2012 (UTC) Dont goI saw that you blanked your page. Frustrated I suppose, understandably! ChemBoxes turned into some some sort of strange obsessive-compulsive venue that I learned to avoid a long time ago. There is one administrator who periodically monitors that ward, upon request: user:Beetstra. Just stick to chemistry - you're really good at it. And we hardly have anyone at your skill level with respect to writing, knowledge, and a sense of humor. The nut-cases do not know enough chemistry to bother people like you and me very often. So I hope you reconsider. We have a lot of stuff to do. So have a beer, and reconsider --Smokefoot (talk) 02:28, 12 July 2012 (UTC)
FluorideRe: [1]. My copy of Greenwood has a section "Fluorides" (Ch. 17, p. 820) that covers both organic and inorganic ones. Materialscientist (talk) 06:31, 14 July 2012 (UTC)
The Medicine ArticlePutting the words Pharmacia and Pharmakea in the medicine article only serves our cause by pushing more relevant information to the top of the search engine when people do a search for Pharmacia or Pharmakea pushing biblical references lower in rank. 2602:306:C518:62C0:1E75:8FF:FEBB:2125 (talk) 16:17, 17 July 2012 (UTC)
You were concerned as I was of the negative connotations toward medicine on the internet when doing a search for the Greek word for medicine Pharmakea. 2602:306:C518:62C0:1E75:8FF:FEBB:2125 (talk) 16:30, 17 July 2012 (UTC) I am beginning to see that salvation comes through YESHUWA not pharmaceuticals. Sorry I am not going to join this conspiracy of yours. Did you know that pharmaceuticals are derived from petrochemicals? Did you know that crude oil is the ancient poop of ancient animals? Do you have a church you can recommend I attend? Maybe you would know since since you are so antiChristian. Please don't take that wrong. You were against the word because you were afraid people would see the Biblical viewpoint of medicine. I am a Christian but I never knew the Greek word for pharmaceutical was in the Bible. It says in Revelation that those practicing pharmakea will be cast in the lake of fire and tormented forever and that a figure called the Whore of Babylon is deceiving the nations with pharmakea. I appreciate you pointing me in the right direction albeit not intentional. If not for you I would have never knew these things. Also crude oil is what lubricates the planet. Bringing that stuff up is causing big earthquakes. 2602:306:C518:62C0:1E75:8FF:FEBB:2125 (talk) 18:33, 17 July 2012 (UTC)
Dispute resolutionIf you are interested, now is a suitable time to contribute to this Wikipedia:ANI#Chembox_edits_by_User:Plasmic_Physics. --Smokefoot (talk) 22:39, 18 July 2012 (UTC)
Atomic massHi. I saw that you reverted my edit in mass number. Here is my rationale for making that edit:
--Farzaneh (talk) 22:33, 22 July 2012 (UTC) FishyTools exist for replacing one word with another. If the mood strikes, you might consider replacing the ridiculous term "ichthyal" with fishy across many articles. It has also occurred to both of us probably that we need some sort of systematic way of correcting the damage done to many pages by Plasmic person. The obvious problems are the names, but there may be subtler defects that require correction. For example, the "related compounds" lists are often too long or point to barely relevant compounds. Ideally one could setting up a mini database on his edits to monitor the progress on undoing the problems. To his credit, he might have been consistently unwise and fetishist, but he may have done good things as well with regards to other aspects of the ChemBox that I dont check.--Smokefoot (talk) 14:08, 31 August 2012 (UTC)
Further on spellingI wondered about Parliment vs Parliament for the man's name but I messed up. Sorry EoGuy (talk) 14:59, 1 September 2012 (UTC) Food sources of phosphorusHello! You believe that information about phosphorus in chocolate is unnecessary in the article Phosphorus. But other articles about nutrients often contain many, sometimes dozens, examples of food sources (look, for example, at Calcium#Nutrition). It is naturally that one reading an article about a nutrient may want to find out which kinds of food contain it. It seems to me that it would be quite interesting after the information about phosphorus in calcium-rich foods to read about an example (chocolate) of food being not calcium-rich, but phosphorus-rich. Now there are only three certain examples there. Maybe, you would agree that 4 examples is not too many yet? --D.M. from Ukraine (talk) 19:23, 1 September 2012 (UTC)
Ethanedithiol prepI saw your note on the industrial prep of this dithiol from NaSH and ethylenedichloride. I expected that this reaction led to excessive thioether formation but maybe there are tricks that avoid this problem. In fact, I teach students that thiols usually cannot be made well from NaSH for this reason. Comments? --Smokefoot (talk) 13:53, 3 September 2012 (UTC)
Harvade, a cotton defoliant, is the biggest application for the ethanedithiol. Never could get anyone to bite on the propanedithiols, but not for lack of trying. I have not been told about any other applications in the last 10-15 years, so I assume this is true.JSR (talk) 14:38, 3 September 2012 (UTC)
Actually, the easiest one to find is the 1997 Kirk-Othmer article on thiols, but I get into trouble quoting that one. I may need to dig into the patent literature to find that one.JSR (talk) 15:14, 3 September 2012 (UTC)
VulcanizationMaybe you know something about the vulcanization of rubber using sulfur? It is almost impossible to find a chemical equation for what happens in that process. Our current image ([[File:Vulcanization of POLYIsoprene V.2.png]]) was contributed by an experienced organic chemist, but he admitted that he was unsure. I was going to upgrade (remove C2S4 ring) using this reaction that begins with activation of an allylic CH and then addition of SH across another double bond:
But maybe you have better sources. I have been itching to get a decent image.--Smokefoot (talk) 19:05, 3 September 2012 (UTC)
Vinyl amine?You might recheck, vinyl amine is unknown. Would be like vinyl alcohol. Also my guess is that cysteamine has hydrogen-bonds from SH to N but is probably not ionized. Someone must have done the structure, but it is not in Cambridge Database. --Smokefoot (talk) 17:11, 18 September 2012 (UTC)
Monty Hall problem RFCHi! Over at Talk:Monty Hall problem#Conditional or Simple solutions for the Monty Hall problem? I assigned Abstain to your comments. If this is incorrect, please indicate "Proposal #1", "Proposal #2", or "Neither". Thanks! --Guy Macon (talk) 20:43, 20 September 2012 (UTC) Concerning the pyrolysis category =Hi John ! I am for sure against spam in WP, and altought I am not the creator of this company's page, it seems that it has been for a while in WP and has not been challenged so far. I believe they have brought some innovation to the field, if you believe they don't deserve to be in WP go ahead and propose theme for deletion I have no problem for it.--Khalid hassani (talk) 15:49, 22 September 2012 (UTC) Interest in sulfur compounds: Dietary SulfurHi. Do you know of any sources/databases detailing the sulfur content of foods? — Preceding unsigned comment added by 212.183.140.19 (talk) 12:31, 23 September 2012 (UTC)
Sulfasalazine removed contentSulfasalazine DOES NOT inhibits dihydrofolate reductase, and DOES NOT cause folate deficiency and megaloblastic anemia, this is a common mistake! Ahmad Al-Tamimi, M.B.B.S. — Preceding unsigned comment added by 87.236.233.3 (talk) 01:19, 26 September 2012 (UTC)
How to ContactDo I understand rightly? You post on my talk page and I post on your talk page? A rather disconnected conversation... SODIUM NITRITE The whole paragraph has no references. "uses in photography" (vague), "electrolyte", "diluted", etc. including the last sentence about "closed loop cooling systems." Should all of that be undone? If I say "as an anti-corrosion additive to industrial greases" then a user would have to search for "industrial grease additive" and may have a difficult time finding info on Sodium Nitrite. If they search the DuPont grease they will have an direct connection to something that I know to be a fact. It is not SPAM and I don't have any connection to DuPont, but I do like examples that allow an encyclopedia to be helpful in my search for knowledge. Perhaps you can tell me how to reference a source which is a webinar produced by DuPont, not guaranteed to remain posted on the web forever or even more than a few months? Should I post a ref to a DuPont data sheet? Babahu (talk) 02:26, 28 September 2012 (UTC)
Please address this issue: The whole paragraph in question has no references. "uses in photography" (vague), "electrolyte", "diluted", etc. including the last sentence about "closed loop cooling systems." Should all of that be undone? — Preceding unsigned comment added by Babahu (talk • contribs) 22:05, 28 September 2012 (UTC)
Thanks, I appreciate all your help. Thanks for fixing my refs. The DuPont ref that talked about the sodium nitrate directly was a pdf and I did not know how to ref to that. The lack of refs I mention has to do with the fact that you removed my addition for lack of a reference and yet I saw no references for the preceding items in that paragraph. I trust the info and I myself don't need refs on those things, but I do want to know when refs are really needed and when not. "Verifiable" can mean you can verify it, but not necessarily that you have to do so in the entry itself or give refs. So I am just learning. Appreciate any opinions on the above. — Preceding unsigned comment added by Babahu (talk • contribs) 23:46, 29 September 2012 (UTC)
Just a thank youI wanted to thank you for your assistance the other day over on wikiproject chemicals! Gzuufy (talk) 04:04, 30 September 2012 (UTC) Dolomite "In Popular Culture": "not particularly useful" (to some) = merits removal (for all)?By that logic, none of the zillions of "In Popular Culture" sections on Wikipedia pages are "particularly useful", so should they all be deleted too? The "In Popular Culture" dimension of Wikipedia must be particularly useful to at least those with an appreciative curiosity (like me) and those specifically researching references to [X] in popular culture, so therefore you believe Wikipedia should explicitly avoid serving such people? I won't start an edit-war over it, I just wish you would reconsider proactive opposition to "In Popular Culture". Acting against any dimension of Wikipedia seems to me is acting against Wikipedia itself. Cheers. — Preceding unsigned comment added by 108.18.224.118 (talk) 16:06, 1 October 2012 (UTC) Your request for rollbackHi JohnSRoberts99. After reviewing your request for rollback, I have enabled rollback on your account. Keep in mind these things when going to use rollback:
If you no longer want rollback, contact me and I'll remove it. Also, for some more information on how to use rollback, see Wikipedia:New admin school/Rollback (even though you're not an admin). I'm sure you'll do great with rollback, but feel free to leave me a message on my talk page if you run into troubles or have any questions about appropriate/inappropriate use of rollback. Thank you for helping to reduce vandalism. Happy editing! Yunshui 雲水 14:04, 4 October 2012 (UTC) GlycineExt Ref is not a spam but refers to the name of tone of the companies in parag thre: "In the USA (by GEO Specialty Chemicals, Inc.) and in Japan (by Shoadenko), glycine is produced via the Strecker amino acid synthesis.[8][9]" Savolya (talk) 15:42, 4 October 2012 (UTC)
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If you do not wish to receive these types of notices, please remove your name from Wikipedia:Feedback request service. — RFC bot (talk) 05:16, 27 October 2012 (UTC) Fuel gasI've started a discussion at Talk:Fuel gas about changing Fuel gas from a disambiguation page back to an article. As you made the change earlier, your input would be appreciated. Thank you. SchreiberBike (talk) 22:59, 27 October 2012 (UTC) MgOHDear John, About MgOH and CaOH: (I have PhD in Organic Chemistry as well.) I noticed there are many different values for solubility of Mg(OH)2, and if you use the numbers in wikipedia, i.e. Ksp and solubility in g/L, they do not come out right. I disagree with your statement, that Ca(OH)2 and Mg(OH)2 do not differ very much in solubility. Actually, they do. Quite much for all practical purposes. Ca(OH)2 is about 0.1% or so, and will maintain pH of 12.5, while Mg(OH)2 is 3-4 orderes of magnitude less, and will keep pH almost intact. This is very important if you need to conduct a pH sensitive reaction. Regards, Nick, 20121025 — Preceding unsigned comment added by 50.193.173.17 (talk) 17:51, 25 October 2012 (UTC) Please comment on Talk:SpamCopGreetings! You have been randomly selected to receive an invitation to participate in the request for comment on Talk:SpamCop. Should you wish to respond to the invitation, your contribution to this discussion will be very much appreciated! If in doubt, please see suggestions for responding. If you do not wish to receive these types of notices, please remove your name from Wikipedia:Feedback request service. — RFC bot (talk) 09:15, 17 November 2012 (UTC) Please comment on Talk:PenisGreetings! You have been randomly selected to receive an invitation to participate in the request for comment on Talk:Penis. Should you wish to respond to the invitation, your contribution to this discussion will be very much appreciated! If in doubt, please see suggestions for responding. 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Legobot (talk) 00:04, 26 May 2015 (UTC) Hi, Please comment on Talk:Dodge TomahawkThe feedback request service is asking for participation in this request for comment on Talk:Dodge Tomahawk. Legobot (talk) 00:04, 10 January 2016 (UTC) Please comment on Template talk:Infobox medical conditionThe feedback request service is asking for participation in this request for comment on Template talk:Infobox medical condition. Legobot (talk) 00:07, 14 January 2016 (UTC) ArbCom Elections 2016: Voting now open!Hello, JohnSRoberts99. Voting in the 2016 Arbitration Committee elections is open from Monday, 00:00, 21 November through Sunday, 23:59, 4 December to all unblocked users who have registered an account before Wednesday, 00:00, 28 October 2016 and have made at least 150 mainspace edits before Sunday, 00:00, 1 November 2016. The Arbitration Committee is the panel of editors responsible for conducting the Wikipedia arbitration process. It has the authority to impose binding solutions to disputes between editors, primarily for serious conduct disputes the community has been unable to resolve. This includes the authority to impose site bans, topic bans, editing restrictions, and other measures needed to maintain our editing environment. The arbitration policy describes the Committee's roles and responsibilities in greater detail. If you wish to participate in the 2016 election, please review the candidates' statements and submit your choices on the voting page. MediaWiki message delivery (talk) 22:08, 21 November 2016 (UTC) Please comment on Talk:Silicon AlleyThe feedback request service is asking for participation in this request for comment on Talk:Silicon Alley. Legobot (talk) 04:26, 30 December 2016 (UTC) Please comment on Talk:Inside (video game)The feedback request service is asking for participation in this request for comment on Talk:Inside (video game). Legobot (talk) 04:27, 3 January 2017 (UTC) Please comment on Category talk:Birds by locationThe feedback request service is asking for participation in this request for comment on Category talk:Birds by location. Legobot (talk) 04:28, 6 January 2017 (UTC) CaffeineHello. Since you promptly reverted me without explaining why, perhaps you'll be kind enough to explain what the sentence means. RivertorchFIREWATER 06:27, 7 January 2017 (UTC) Magnesium hydroxidePlease explain why you have reverted my edits on the basicity of magnesium hydroxide. The value you have restored (pKb = 2.6) is completely unsourced and does not specify what reaction it refers to: Brønsted basicity to give Mg(OH)(OH2)+ or dissociation of OH-. I have found a source which gives two values: Kb1 for dissociation from Mg(OH)2 and Kb2 for dissociation from Mg(OH)+. If this is incorrect I would like to know why. Unsourced and unexplained values are not supposed to stay in Wikipedia, especially if sources are available. Dirac66 (talk) 02:59, 7 January 2017 (UTC)
Please comment on Talk:Milky WayThe feedback request service is asking for participation in this request for comment on Talk:Milky Way. Legobot (talk) 04:26, 10 January 2017 (UTC) Removal of sourced contentI have no idea what is up with this, but that reversion is unsustainable under any policy or guideline.
Please comment on Talk:MasturbationThe feedback request service is asking for participation in this request for comment on Talk:Masturbation. Legobot (talk) 04:25, 14 January 2017 (UTC) AKDOK, I put up a skeletal article on AKD and ASA. Please edit or leave comments so that we can get this thing to the level that it is helpful to reader. Some possible art: picture of an ASA. Most important might be a picture of the reactions of AKD and ASA with cellulose, although it is not clear if this aspect is really known. Some comment on the different ways ASA and AKDs are deployed would be appropriate. --Smokefoot (talk) 16:29, 15 January 2017 (UTC) Please comment on Talk:Earthquake predictionThe feedback request service is asking for participation in this request for comment on Talk:Earthquake prediction. Legobot (talk) 04:26, 17 January 2017 (UTC) Weight of Fuel ?A tank containing say 10,000L of fuel is to be lifted. Ignoring the weight of tank itself, how heavy would the tank weigh if filled fully? Wikipedia does not seem to say succinctly, if at all, how heavy different kinds of fuel weigh. Can you provide these answers, for say
Ethanol RemovalThanks for telling me about you reverting my Ethanol edit. The article might have had some bias signs in it. Cass — Preceding unsigned comment added by Cassini127 (talk • contribs) 01:15, 20 January 2017 (UTC) Please comment on Talk:EuphoriaThe feedback request service is asking for participation in this request for comment on Talk:Euphoria. Legobot (talk) 04:24, 21 January 2017 (UTC) Please comment on Talk:Anatole KlyosovThe feedback request service is asking for participation in this request for comment on Talk:Anatole Klyosov. Legobot (talk) 04:27, 24 January 2017 (UTC) Please comment on Talk:JavaScript templatingThe feedback request service is asking for participation in this request for comment on Talk:JavaScript templating. Legobot (talk) 04:27, 27 January 2017 (UTC) Please comment on Talk:PedophiliaThe feedback request service is asking for participation in this request for comment on Talk:Pedophilia. Legobot (talk) 04:25, 31 January 2017 (UTC) Please comment on Talk:Nintendo SwitchThe feedback request service is asking for participation in this request for comment on Talk:Nintendo Switch. Legobot (talk) 04:26, 4 February 2017 (UTC) Please comment on Talk:Coal pollution mitigationThe feedback request service is asking for participation in this request for comment on Talk:Coal pollution mitigation. Legobot (talk) 04:25, 8 February 2017 (UTC) Please comment on Talk:Hsiung Feng IIIThe feedback request service is asking for participation in this request for comment on Talk:Hsiung Feng III. Legobot (talk) 04:25, 12 February 2017 (UTC) Please comment on Talk:DoxycyclineThe feedback request service is asking for participation in this request for comment on Talk:Doxycycline. Legobot (talk) 04:26, 15 February 2017 (UTC) Then migraine section should be deleted toovery similar to the one I found, and for the other 6 diseases it says there is no benefit, and those sections are allowed to stand but not my contribution — Preceding unsigned comment added by Granito diaz (talk • contribs) 21:09, 16 February 2017 (UTC)
Please comment on Wikipedia talk:WikiProject ChemistryThe feedback request service is asking for participation in this request for comment on Wikipedia talk:WikiProject Chemistry. Legobot (talk) 04:25, 19 February 2017 (UTC) Again, why does my edit gets COMPLETELY OBLITERATED?It cannot be restored, in case it is proven right. Doesn't make sense, you had already deleted it, it was not visible to anyone, why delete it completely?
Please comment on Talk:List of sport utility vehiclesThe feedback request service is asking for participation in this request for comment on Talk:List of sport utility vehicles. Legobot (talk) 04:26, 23 February 2017 (UTC) Please comment on Talk:Robert SungenisThe feedback request service is asking for participation in this request for comment on Talk:Robert Sungenis. Legobot (talk) 04:26, 28 February 2017 (UTC) It doesn't matter, but then again maybe it does
--Smokefoot (talk) 03:25, 12 March 2017 (UTC) Smokefoot, thanks.JSR (talk) 01:09, 13 March 2017 (UTC) Please comment on Talk:List of scientists opposing the mainstream scientific assessment of global warmingThe feedback request service is asking for participation in this request for comment on Talk:List of scientists opposing the mainstream scientific assessment of global warming. Legobot (talk) 04:25, 20 March 2017 (UTC) Thank youThank you for your correction. I apologize for my error. Please feel free to check up on my editing any time. btw - you are amazingly prolific for a newer editor. I appreciate your work and I am very impressed.
Please comment on Talk:Borderline personality disorderThe feedback request service is asking for participation in this request for comment on Talk:Borderline personality disorder. Legobot (talk) 04:24, 7 April 2017 (UTC) Please comment on Wikipedia talk:WikiProject AstronomyThe feedback request service is asking for participation in this request for comment on Wikipedia talk:WikiProject Astronomy. Legobot (talk) 04:26, 14 April 2017 (UTC) Please comment on Template talk:Infobox softwareThe feedback request service is asking for participation in this request for comment on Template talk:Infobox software. Legobot (talk) 04:25, 18 April 2017 (UTC) What I heard ...I asked around but did not get a clear answer about the thionyl chloride reactivity - giving alkyl chloride vs sulfite ester. It may well be stoichiometry, such that heating ROS(O)Cl, HCl with a trace of SOCl2 or other Lewis acid would give the alkyl chloride. My organic colleague did explain that the mechanism changes for tertiary vs primary alcohols. I notice that Voss et all keep temp low and sparge to remove HCl. --Smokefoot (talk) 23:39, 18 April 2017 (UTC)
On the page NFPA 704, it states that a compound with a flash point above 93.3 oC is considered to have a rating of 1. THe flash point stated in the trinitrotoluene article is 167 oC. Should I not be using this? Thanks, RedPanda25 21:17, 19 April 2017 (UTC)
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Tech news prepared by Tech News writers and posted by bot • Contribute • Translate • Get help • Give feedback • Subscribe or unsubscribe. 19:50, 1 May 2017 (UTC) Please comment on Talk:Economic Freedom of the WorldThe feedback request service is asking for participation in this request for comment on Talk:Economic Freedom of the World. Legobot (talk) 04:24, 2 May 2017 (UTC) SockRegarding [12], he's actually never left...WP:RBI and get on with your better life that theirs:) Feel free to ping me for the "B" part of that or to dig further. Often one edit helps find some sleeper/old ones that were not on our watchlists. DMacks (talk) 04:04, 3 May 2017 (UTC) Please comment on Talk:MicroscopeThe feedback request service is asking for participation in this request for comment on Talk:Microscope. Legobot (talk) 04:25, 5 May 2017 (UTC) Please comment on Talk:CarThe feedback request service is asking for participation in this request for comment on Talk:Car. Legobot (talk) 04:26, 8 May 2017 (UTC) [13]
Hello JohnSRoberts,
There was a source for 1, but not 2 or 3, so I changed 2. Can you please tell me what I did wrong?
Thanks, RedPanda25 15:05, 8 May 2017 (UTC)
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Hello JohnSRoberts,
Yes, that could work. But why not just tetrahedral? I really don't find much on the subject in any major source. Maybe Smokefoot can come up with an Ulmann's source? JSR (talk) 23:04, 8 May 2017 (UTC)
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