Marie (1639–1715), the third sister, was considered the least beautiful of the sisters but was the one who snagged the biggest prize of all: Louis XIV. The young king was so besotted with her that he wanted to marry her. In the end, he was made to give her up, and she married Prince Lorenzo Colonna who remarked that he was surprised to find her a virgin as one does not expect to find 'innocence among the loves of kings'. (from Antonia Fraser's book Love and Louis XIV)
One of Marie Anne's brothers was Philippe Jules Mancini, a lover of Philippe de France, brother of Louis XIV. Marie Anne's uncle died when she was thirteen. The night before the cardinal's death, the famous field marshal Turenne came to his bedside to ask for the hand of Marie Anne in the name of his nephew, the young Godefroy Maurice, Duke of Bouillon.
The couple were married in the presence of the Royal family at the Louvre Palace in Paris on 19 April 1662. The marriage produced seven children, three of which would go on to produce children. His wife raised her nephew Louis Joseph de Bourbon, the orphan son of Laure Mancini and Louis de Bourbon.
His wife established a small salon at her new residence, the Hôtel de Bouillon, which he bought in 1681. He outlived his wife by some seven years. He was succeeded by his son Emmanuel Theodose as the Duke of Bouillon.
Louise Julie de La Tour d'Auvergne, Mademoiselle de Château-Thierry (26 November 1679–21 November 1750) married François Armand, Prince of Guéméné and had a child who died aged 3.