Fluorocyclopropane

Fluorocyclopropane
Names
Preferred IUPAC name
Fluorocyclopropane
Other names
Cyclopropyl fluoride, cyclopropylfluoride
Identifiers
3D model (JSmol)
ChemSpider
EC Number
  • 212-459-6
  • InChI=1S/C3H5F/c4-3-1-2-3/h3H,1-2H2
    Key: XAVRRVJJYIFROR-UHFFFAOYSA-N
  • C1CC1F
Properties
C3H5F
Molar mass 60.071 g·mol−1
Density g/cm3
Insoluble
Related compounds
Related compounds
 Chlorocyclopropane
Bromocyclopropane
Iodocyclopropane
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Fluorocyclopropane is an organofluorine compound with the chemical formula C3H5F. The compound is a member of haloalkane family.[1]

Synthesis

The compound can be produced by reacting imidazolylidene cyclopropyl group with xenon difluoride.[2]

Also, a reaction of enantioselective cyclopropanation of fluoro-substituted allylic alcohols using zinc carbenoids.[3]

See also

References

  1. ^ Kerr, J. A.; Kirk, A. W.; O'Grady, B. V.; Phillips, D. C.; Trotman-Dickenson, A. F. (1967). "Kinetics of decomposition of chemically activated alkyl fluorides". Discussions of the Faraday Society. 44: 263. doi:10.1039/DF9674400263. Retrieved 29 May 2023.
  2. ^ Mankad, Neal P.; Toste, F. Dean (2012). "C(sp 3 )–F reductive elimination from alkylgold( iii ) fluoride complexes". Chem. Sci. 3 (1): 72–76. doi:10.1039/C1SC00515D. PMC 3474378. Retrieved 29 May 2023.
  3. ^ Delion, Laëtitia; Poisson, Thomas; Jubault, Philippe; Pannecoucke, Xavier; Charette, André B. (September 2020). "Synthesis of fluorocyclopropanes via the enantioselective cyclopropanation of fluoro-substituted allylic alcohols using zinc carbenoids". Canadian Journal of Chemistry. 98 (9): 516–523. doi:10.1139/cjc-2020-0036. ISSN 0008-4042. Retrieved 29 May 2023.

Extra reading

  • Dall'O, L.; Heydtmann, H. (January 1987). "Kinetic Study of Chemically Activated Fluorocyclopropane". Berichte der Bunsengesellschaft für physikalische Chemie. 91 (1): 24–30. doi:10.1002/bbpc.19870910107.
  • Casas, F.; Kerr, J. A.; Trotman-Dickenson, A. F. (1964). "706. Fluorinated cyclopropanes. Part II. The thermal isomerization of monofluorocyclopropane". Journal of the Chemical Society (Resumed): 3655. doi:10.1039/JR9640003655.