Boratabenzene

Boratabenzene

Names
IUPAC name Boranuidabenzene
Identifiers
CAS Number	55926-39-1^Y
3D model (JSmol)	Interactive image
InChI InChI=1S/C5H6B/c1-2-4-6-5-3-1/h1-3,6H,4H2/q-1 Key: QPSALOYQXJTXAR-UHFFFAOYSA-N
SMILES [BH-]=1CC=CC=C1
Properties
Chemical formula	C5H6B^−
Molar mass	76.91 g·mol^−1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Structure of Rh(C₈H₁₂)(η^6-C₅H₅BH).[1]

Boratabenzene is the heteroaromatic anion with the formula [C₅H₅BH]^−. Derivatives of boratabenzene are ligands akin to cyclopentadienyl anion. sandwich or half-sandwich type complexes of many transition metals have been reported.[2][3] Electronically related heterocycles are adducts of borabenzene. The adduct C₅H₅B·pyridine exhibits properties of boratabenzene anion, i.e., it has the character C₅H₅B^−-N^+C₅H₅.

See also

• borabenzene, silabenzene, germabenzene, stannabenzene, pyridine, phosphorine, arsabenzene, bismabenzene, pyrylium, thiopyrylium, selenopyrylium, telluropyrylium
• Borazine

References

1. Yuan, Yuanyuan; Wang, Xiufang; Li, Yuxue; Fan, Liyan; Xu, Xin; Chen, Yaofeng; Li, Guangyu (2011). "Rapid Entry to Functionalized Boratabenzene Complexes through Metal-Induced Hydroboration at the Anionic 1-H-Boratabenzene Ligand". Organometallics. 30 (16): 4330–4341. doi:10.1021/om200396k.
2. Janiak, Christoph (2006). "Metallocene and Related Catalysts for Olefin, Alkyne and Silane Dimerization and Oligomerization". Coordination Chemistry Reviews. 250 (1–2): 66–94. doi:10.1016/j.ccr.2005.02.016.
3. Cui, Peng; Chen, Yaofeng (2016). "Boratabenzene Rare-earth Metal Complexes". Coordination Chemistry Reviews. 314: 2–13. doi:10.1016/j.ccr.2015.07.014.