9,10-二硒杂蒽或硒蒽是一种有机硒化合物,化学式为C12H8Se2。它可由邻苯二基汞和硒反应制得,[2]或由1,2-二碘苯、碳酸铯和硒氰酸钾在催化下反应得到。[3]它和三氯化铝在90 °C、1 Pa下反应,可以得到[Al(C12H8Se2)3][Al2Cl7]3。[4]
参考文献
- ^ 1.0 1.1 Formation of Selenanthrene from Diphenyl Selenide and of Dipotassium Triimidotellurite from Diphenyl Telluride. Angew Chem Int Ed. 1967. doi:10.1002/anie.196710711.
- ^ Humphries, R. E., Al-Jabar, N. A. A., Bowen, D., Massey, A. G., & Deacon, G. B. (1987). Transmetallation reactions involving phenylenemercurials. Journal of Organometallic Chemistry, 319(1), 59–67. doi:10.1016/0022-328x(87)80347-9
- ^ Potassium selenocyanate as an efficient selenium source in C–Se cross-coupling catalyzed by copper iodide in water. Tetrahedron Letters, 2011. 52 (31). doi:10.1016/j.tetlet.2011.05.068.
- ^ The Reactions of Thianthrene and Selenanthrene with AlCl3: Coordination Complexes, Radical Ions, and Investigations on the Unique Triple-Decker Molecule (Thianthrene)32+. EurJIC. 2012. doi:10.1002/ejic.201200067.